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One-dimensional inorganic-organic hybrid material [Cu(En)2]2H2[{Cu(En)2}2(H2W12O42)] · 6.5H2O: Hydrothermal syntheses and crystal structure

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Abstract

A novel inorganic-organic hybrid material, [Cu(En)2]2H2[{Cu(En)2}2(H2W12O42)] · 6.5H2O (I) based on polyoxotungstates and Cu2+ ions, has been successfully synthesized under hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction, IR spectra, and TG analysis. Structural analysis indicates that the structure consists of a one-dimensional structure constructed from the polyoxoanion [H2W12O42]10− bridged by {Cu(En)2}2+ groups. Each [H2W12O42]10− cluster in the polymeric chain is linked to two neighbors through four coordination groups of μ2-[Cu(En)2]2+. Furthermore, it extends into a three-dimensional supramolecular network by hydrogen bonding interactions.

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References

  1. Hagrman, P.J., Hagrman, D., and Zubieta, J., Angew. Chem. Int. Ed., 1999, vol. 38, p. 2638.

    Article  Google Scholar 

  2. Zhang, P.P., Tian, A.X., Peng, J., et al., Inorg. Chem. Commun., 2009, vol. 12, p. 902.

    Article  CAS  Google Scholar 

  3. Yin, C.X. and Finke, R.G., J. Am. Chem. Soc., 2005, vol. 127, p. 9003.

    Article  CAS  Google Scholar 

  4. Khenkin, A.M., Weiner L., and Neumann, R., J. Am. Chem. Soc., 2005, vol. 127, p. 9988.

    Article  CAS  Google Scholar 

  5. Manos, M.J., Tasiopoulos, A.J., Tolis, E.J., et al., Chem. Eur. J., 2003, vol. 9, p. 695.

    Article  CAS  Google Scholar 

  6. Mialane, P., Duboc, C., Marrot, J., et al., Chem. Eur. J., 2006, vol. 12, p. 1950.

    Article  CAS  Google Scholar 

  7. Pope, M.T. and Muller, A., Angew. Chem., Int. Ed., 1991, vol. 30, p. 34.

    Article  Google Scholar 

  8. Sadakane, M., Dickman, M.H., and Pope M.T., Angew. Chem. Int. Ed., 2000, vol. 39, p. 2914.

    CAS  Google Scholar 

  9. Kin, K.C. and Pope, M.T., J. Am. Chem. Soc., 1999, vol. 121, p. 8512.

    Article  Google Scholar 

  10. Zhang, J.J., Sheng, T.L., Xia, S.Q., et al., Inorg. Chem., 2004, vol. 43, p. 5472.

    Article  CAS  Google Scholar 

  11. Zheng, S.L., Yang, J.H., Yu, X.L., et al., Inorg. Chem., 2004, vol. 43, p. 830.

    Article  CAS  Google Scholar 

  12. Muller, A., Pope, M.T., and Gatteschi, D., Chem. Rev., 1998, vol. 98, p. 239.

    Article  Google Scholar 

  13. Devi, R.N. and Zubieta, J., Inorg. Chim. Acta., 2002, vol. 338, p. 165.

    Article  Google Scholar 

  14. Zhang, Y., Zapf, P.J., Meyer, L.M., et al., Inorg. Chem., 1997, vol. 36, p. 2159.

    Article  CAS  Google Scholar 

  15. Finn, R.C. and Zubieta, J., Chem. Commun., 2000, p. 1321.

  16. Zak, Z., Perutka, J., Havel, J., et al., J. Alloys Comp., 1998, vol. 281, p. 169.

    Article  CAS  Google Scholar 

  17. Lisnard, L., Dolbecq, A., Mialane, P., et al., Inorg. Chim. Acta, 2004, vol. 357, p. 845.

    Article  CAS  Google Scholar 

  18. Lin, B.Z., Chen, Y.M., and Liu, P.D., Dalton. Trans., 2003, p. 2474.

  19. Yan, B.B., Goh, N.K., and Chia, L.S., Inorg. Chim. Acta, 2004, vol. 357, p. 490.

    Article  CAS  Google Scholar 

  20. Sheldrick, G.M., SHELXTL-97, Program for Crystal Structure Refinement, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  21. Sheldrick, G.M., SHELXS-97, Program for Crystal Structure Solution, Göttingen (Germany): Univ. of Göttingen, 1997.

    Google Scholar 

  22. Allmann, V.R., Acta Crystallogr., B, 1971, vol. 27, p. 1393.

    Article  CAS  Google Scholar 

  23. Tsay, Y.H. and Silverton, J.V., Z. Kristallogr., 1973, vol. 137, p. 256.

    CAS  Google Scholar 

  24. Evans, H.T., Kortz, U., and Jameson, G.B., Acta Crystallogr., C, 1993, vol. 49, p. 856.

    Article  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, 350007, P.R, China

    Y. Yuan, Q. S. Wang & S. M. Wang

  2. State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou, 350002, P.R. China

    S. M. Wang

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  1. Y. Yuan
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  2. Q. S. Wang
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  3. S. M. Wang
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Correspondence to S. M. Wang.

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Yuan, Y., Wang, Q.S. & Wang, S.M. One-dimensional inorganic-organic hybrid material [Cu(En)2]2H2[{Cu(En)2}2(H2W12O42)] · 6.5H2O: Hydrothermal syntheses and crystal structure. Russ J Coord Chem 37, 528–534 (2011). https://doi.org/10.1134/S107032841106011X

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  • DOI: https://doi.org/10.1134/S107032841106011X

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