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Copper(II) complex with thienyltrifluoroacetylacetone and dimethyl sulfoxide: Synthesis and crystal structure

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Abstract

A new copper(II) complex with thienyltrifluoroacetone (Tfa) and dimethyl sulfoxide (DMSO), Cu(Tfa)2DMSO, was synthesized, and its X-ray diffraction analysis was carried out. The crystals were triclinic: a = 9.4496(5), b = 10.5075(6), c = 11.9160(6) Å, α = 82.600(1)°, β = 84.116(1)°, γ = 77.904(1)°, V = 1143.8(1) Å3, space group P \( \bar 1 \), Z = 2, ρcalcd = 1.696 mg/m3, R = 0.0700. The environment of the copper atom was formed by four oxygen atoms of two thienyltrifluoroacetylacetone molecules and one oxygen atom of DMSO.

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Authors and Affiliations

  1. Baku State University, Baku, Azerbaijan

    A. M. Magerramov, R. A. Alieva, F. N. Bakhmanova, F. M. Chyragov & R. K. Askerov

  2. Islamic Independent University of Iran, Tehran, Iran

    R. N. Sulhnejat

  3. Vladimir State University, Vladimir, Russia

    K. A. Potekhin

Authors
  1. A. M. Magerramov
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  2. R. A. Alieva
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  3. F. N. Bakhmanova
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  4. R. N. Sulhnejat
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  5. F. M. Chyragov
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  6. R. K. Askerov
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  7. K. A. Potekhin
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Corresponding author

Correspondence to F. N. Bakhmanova.

Additional information

Original Russian Text © A.M. Magerramov, R.A. Alieva, F.N. Bakhmanova, R.N. Sulhnejat, F.M. Chyragov, R.K. Askerov, K. A. Potekhin, 2011, published in Koordinatsionnaya Khimiya, 2011, Vol. 37, No. 1, pp. 46–48.

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Magerramov, A.M., Alieva, R.A., Bakhmanova, F.N. et al. Copper(II) complex with thienyltrifluoroacetylacetone and dimethyl sulfoxide: Synthesis and crystal structure. Russ J Coord Chem 37, 45–47 (2011). https://doi.org/10.1134/S1070328410121048

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  • DOI: https://doi.org/10.1134/S1070328410121048

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