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Complex formation of 2,4,6-triallyloxy-1,3,5-triazine with copper(I,II) chloride. Synthesis and crystal structure of the Cu3Cl4 · 2C3N3(OC3H5)3 π-complex

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Abstract

The mixed-valence Cu3Cl4 · 2C3N3(OC3H5)3 π-complex (I) is synthesized from 2,4,6-triallyloxy-1,3,5-triazine (L) and copper(II) chloride by the alternating-current electrochemical method in an ethanolic solution. Single crystals of complex I are studied by X-ray diffraction analysis: space group I41/a, a = 25.39(8), c = 10.14(6) Å, V = 6537(48) Å3, Z = 8, R = 0.0814. The copper(I) and chlorine atoms form unique cyclic tetramers Cu4Cl4. The coordination sphere of each copper(I) atom includes the C=C bond of the allyl group of the ligand molecule L in addition to the two bridging chlorine atoms. Two nearest triazine rings are coordinated through the nitrogen atoms to the copper(II) atoms, whose environment is completed to a square with two chlorine atoms. An intricate three-dimensional structure is formed due to the μ4-bridging function of the cupro(I) tetramer and the μ2-bridging function of the ligand molecule L.

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Authors and Affiliations

  1. J. Stefan Institute, Ljubljana, Slovenia

    E. A. Goreshnik

  2. Franko National University, ul. Kirilla i Mefodiya 6, Lviv, 7905, Ukraine

    M. G. Mys’kiv

Authors
  1. E. A. Goreshnik
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  2. M. G. Mys’kiv
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Correspondence to M. G. Mys’kiv.

Additional information

Original Russian Text © E.A. Goreshnik, M.G. Mys’kiv, 2008, published in Koordinatsionnaya Khimiya, 2008, Vol. 34, No. 6, pp. 451–455.

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Goreshnik, E.A., Mys’kiv, M.G. Complex formation of 2,4,6-triallyloxy-1,3,5-triazine with copper(I,II) chloride. Synthesis and crystal structure of the Cu3Cl4 · 2C3N3(OC3H5)3 π-complex. Russ J Coord Chem 34, 443–447 (2008). https://doi.org/10.1134/S1070328408060092

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  • DOI: https://doi.org/10.1134/S1070328408060092

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