Abstract
The synthesis of a new Schiff base derived from 2-hydroxy-5-chloroacetophenone and 4-amino-5-mercapto-3-methyl-1,2,4-triazole and its coordination compounds with Ti(III), VO(IV), Cr(III), Mn(III), Fe(III), Zr(IV), MoO2(VI), and UO2(VI) are described. The ligand and the complexes have been characterized on the basis of analytical, electrical conductance, molecular weight, IR and electronic spectra, magnetic susceptibility measurements, and thermogravimetric analysis. The ligand acts as a dibasic tridentate molecule. Antibacterial activities of the ligand and its metal complexes have been determined by screening the compounds against E. coli, S. typhi, P. aeruginosa, and S. aureus. The solid state de electrical conductivity of the ligand and its complexes have been measured over 313–403 K, and the complexes were found to be of semiconducting nature.
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Tarafdar, M., Tofazzal, H., Ali, M.A., et al., Trans. Met. Chem., 2000, vol. 25, no. 4, p. 456.
Singh, R. V. and Pandey, T., Main Group Met. Chem., 2000, vol. 23, p. 345.
Mourya, M.R., Agarwal S., Abid M., et al., Dalton Trans., 2006, p. 1.
Singh R. V., Gurg, R., Saini, M. K., and Fatimi, N., Indian J. Chem., 2005, vol. 44, p. 2433.
Hankare, P.P., Patil, R.K., Chavan, S.S., et al., Indian J. Chem., 2001, vol. 40, p. 1326.
Dhaka, K.S., Mohan, J., Chaddha, V.K., and Pujari, H.K., Indian J. Chem., 1974, vol. 12, p. 287.
Christensen, O.T., Z. Anorg. Chem., 1901, vol. 27, p. 325.
Mandlik, P.R. and Aswar, A.S., Polish J. Chem., 2003, vol. 77, p. 129.
Maurya, M.R., Khurana, S., Azam, A., et al., Eur. J. Inorg. Chem., 2003, p. 1966.
Singh, G., Singh, A., Singh, K., et al., Proc. Nat. Acad. Sci., 2002, vol. 72, p. 87.
Aswar A.S. and Mandlik P.R., Indian J. Chem., 2003, vol. 42, p. 1064.
Mishra, A.P and Pandey, L.R., Indian J. Chem., 2005, vol. 44, p. 94.
Horowitz, H.H. and Metzger, G., J. Anal. Chem., 1963, vol. 35, p. 1954.
Coats, A.W. and Redfern, J.P., Nature, 1964, vol. 201, p. 68.
Piloyan, G.O., Pyabonikar, T.D., and Novikova, C.S., Nature, 1966, vol. 212, p. 1229.
Srivastava, R.S., Inorg. Chem. Acta, 1981, vol. 56, p. 165.
Aswar, A.S., Mohod, R.B., and Bhadange, S.G., Indian J. Chem., 2001, vol. 40, p. 1110.
Anantnarayan, R. and Jairam Panikar, C.K., Text Book of Microbiology, Orient Longman, India, 1996, p. 578.
Thangadurai, D. and Natarajan, K., Synth. React. Inorg. Met.-Org. Chem., 2001, vol. 30, p. 569.
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Badwaik, V.B., Aswar, A.S. Synthesis, characterization, and biological studies of some Schiff base complexes. Russ J Coord Chem 33, 755–760 (2007). https://doi.org/10.1134/S1070328407100077
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DOI: https://doi.org/10.1134/S1070328407100077