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Use of Background Concentrations of Heavy Metals for Regional Monitoring of Soil Contamination by the example of Rostov Oblast

  • DEGRADATION, REHABILITATION, AND CONSERVATION OF SOILS
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Abstract

In the monitoring of soils contaminated with heavy metals, the choice of the target indicators (background or threshold values) is a challenging task. The determination of the background concentrations is of practical importance, because the pollution of clean soils to the levels below the maximum permissible concentration (MPC) or the tentative permissible concentration (TPC) levels is not recorded and, hence, cannot be prosecuted. Background concentrations are rarely applied in pollution assessment, because they remain unknown in most cases. The study of the soils of specially protected natural areas in Rostov oblast has revealed the regional specificity of the soil cover—elevated concentrations of a number of heavy metals and other trace elements—related to their high concentrations in the parent materials. Therefore, it is impossible to apply current public health standards based on the total concentrations of elements, such as MPC and TPC, in the monitoring of soil contamination in Rostov oblast. The use of background values characterizing the soils of specially protected natural areas seems to be more promising for this purpose. For an adequate environmental monitoring, data on the background concentrations of trace elements in the virgin of slightly transformed soils of specially protected natural areas should be obtained with due account for the regional diversity of soils including their classification position, texture, and the character of parent materials.

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REFERENCES

  1. Agroecological Assessment of Lands and Design of Adaptive-Landscape Farming Systems and Agricultural Technologies: Methodological Issues, Ed. by V. I. Kiryushin and A. L. Ivanov (Moscow, 2005) [in Russian].

    Google Scholar 

  2. E. V. Arinushkina, Handbook on the Chemical Analysis of Soils (Moscow State Univ., Moscow, 1970) [in Russian].

    Google Scholar 

  3. V. A. Bol’shakov, N. N. Ladonina, and A. S. Frid, “Mapping of point and area pollution in cities,” Eurasian Soil Sci. 35, 559–562 (2002).

    Google Scholar 

  4. A. P. Vinogradov, Geochemistry of Rare and Dispersed Chemical Elements in Soils (Academy of Sciences of USSR, Moscow, 1957) [in Russian].

    Google Scholar 

  5. L. Yu. Goncharova, T. M. Minkina, S. S. Mandzhieva, A. K. Sherstnev, O. A. Biryukova, N. E. Kravtsova, and I. V. Zamulina, “Modern states of ordinary chernozems in specially protected natural territories in the Lower Don region,” Nauchn. Zh. Ross. Nauchno-Issled. Inst. Probl. Melioratsii, No. 4, 200–227 (2015).

    Google Scholar 

  6. S. N. Gorbov, O. S. Bezuglov, A. S. Aleksikova, S. S. Tagiverdiev, M. N. Dubinina, and A. K. Sherstnev, “The content and distribution of heavy metals and arsenic in soils of Rostov-on-Don,” Sovrem. Probl. Nauki Obraz., No. 4, (2015). http://www.science-education.ru/ru/article/view?id=21428.

  7. V. V. D’yachenko and I. Yu. Matasova, “Pollution and dynamics of trace elements in soils of the south of Russia,” Geol., Inzh. Geol., Gidroekol., Geokriol., No. 4, 324–332 (2015).

  8. V. V. D’yachenko and I. Yu. Matasova, “Regional clarkes of chemical elements in soils of southern European Russia,” Eurasian Soil Sci. 49, 1091–1098 (2016). https://doi.org/10.1134/S1064229316100069

    Article  Google Scholar 

  9. V. E. Zakrutkin, N. I. Koronkevich, D. Yu. Shishkina, and S. V. Dolgov, Anthropogenic Transformation of Small Watersheds in the Steppe Zone of Southern Russia within Rostov Oblast (Rostov State Univ., Rostov, 2004) [in Russian].

    Google Scholar 

  10. Yu. N. Zborishchuk, “Relative abundance ratios of physiologically important trace elements in soils,” Vestn. Mosk. Univ., Ser. 17: Pochvoved., No. 4, 18–21 (1977).

  11. N. G. Zyrin, “Distribution and dynamics of the content of trace elements in soils of the Russian Plain,” Pochvovedenie, No. 7, 77–88 (1968).

    Google Scholar 

  12. V. B. Il’in, Heavy Metals in the Soil-Plant System (Novosibirsk, 1991) [in Russian].

    Google Scholar 

  13. A. Kabata-Pendias and H. Pendias, Trace Elements in Soils and Plants (CRC Press, Boca Raton, 1983; Mir, Moscow, 1989).

  14. O. A. Kapralova and S. I. Kolesnikov, “The effect of heavy metal pollution on the ecological and biological properties of soils in Rostov-on-Don city,” Nauchn. Mysl’ Kavk., No. 1 (69), (2012).

  15. Classification and Diagnostics of Soils of the Soviet Union (Kolos, Moscow, 1977) [in Russian].

  16. M. F. Kuznetsov, Trace Elements in Soils of Udmurtia (Izhevsk, 1994) [in Russian].

    Google Scholar 

  17. Yu. M. Matveev, I. V. Popova, and O. V. Chernova, “Standardization of the content of chemical compounds in soil,” Agrokhimiya, No. 12, 54–60 (2001).

    Google Scholar 

  18. M-049-P/10: Measurement of the Mass Fraction of Metals and Metal Oxides in Powder Samples of Soils by X-Ray Fluorescence (St. Petersburg, 2010) [in Russian].

  19. Evaluation of Hazardous Environmental Risk (Land) Approved by the Order No. 17 of November 29, 2002 by Head of Environment Protection Department of Tomsk Oblast (Tomsk, 2002) [in Russian]. http://green.tsu.ru/htmls/doc/zakon

  20. Manual for Identification of Degraded and Polluted Lands (State Committee of the Russian Federation on Land Resources and Land Management, Moscow, 1995) [in Russian].

  21. Manual for Hygienic Substantiation of Maximum Permissible Concentrations of Chemical Substances in Soil (Moscow, 1982) [in Russian].

  22. Manual for Assessment of the Risk of Soil Pollution by Chemical Substances (Ministry of Health of USSR, Moscow, 1987) [in Russian].

  23. T. M. Minkina, G. V. Motuzova, S. S. Mandzhieva, O. G. Nazarenko, M. V. Burachevskaya, and E. M. Antonenko, “Fractional and group composition of the Mn, Cr, Ni, and Cd compounds in the soils of technogenic landscapes in the impact zone of the Novocherkassk Power Station,” Eurasian Soil Sci. 46, 375–385 (2013).

    Article  Google Scholar 

  24. The procedure for determination of the hazardous loss due to land pollution by chemical substances approved by the State Committee of the Russian Federation on Land Resources and Land Management on November 10, 1993 and by the Ministry of the Environment of the Russian Federation on November 18, 1993, Database of regulatory documentation. http//www.complexdoc.ru.

  25. N. A. Protasova, A. P. Shcherbakov, and M. T. Kopaeva, Rare and Dispersed Elements in Soils of the Central Chernozemic Region (Voronezh, 1992) [in Russian].

    Google Scholar 

  26. A. T. Savichev, “Causes of errors in the determination of macroelements in soils and hard rocks using the X-ray fluorescence method,” Eurasian Soil Sci. 40, 32–36 (2007).

    Article  Google Scholar 

  27. A. T. Savichev and S. E. Sorokin, “X-ray fluorescent analysis of the content of trace elements and heavy metals in soils,” Agrokhimiya, No. 12, 71–74 (2000).

    Google Scholar 

  28. O. A. Samonova and E. N. Aseeva, “Geochemical transformation of surface and moraine loamy soils in the middle reaches of the Protva River during pedogenesis,” Vestn. Mosk. Univ., Ser. 5: Geogr., No. 6, 67–74 (2006).

  29. D. Yu. Shishkina, Heavy Metals in Soils of Rostov-on-Don (Rostov-on-Don, 2017) [in Russian].

    Google Scholar 

  30. O. S. Bezuglova, S. N. Gorbov, S. A. Tischenko, A. S. Aleksikova, S. S. Tagiverdiev, A. K. Sherstnev, and M. N. Dubinina, “Accumulation and migration of heavy metals in soils of the Rostov region, south of Russia,” J. Soils Sediments 16 (4), 1203–1213 (2016). doi 1007/s11368-015-1165-8

  31. Derivation Methods of Soil Screening Values in Europe. A Review and Evaluation of National Procedures towards Harmonization, Ed. by C. Carlon (European Commission, Joint Research Centre, Ispra, 2007), No. EUR 22805-EN.

  32. D. Heemsbergen, M. Warne, M. McLaughlin, and R. Kookana, The Australian Methodology to Derive Ecological. Investigation Levels in Contaminated Soils: CSIRO Land and Water Science Report 43/09 (Commonwealth Scientific and Industrial Research Organization, Canberra, 2009).

    Google Scholar 

  33. T. M. Minkina, D. G. Nevidomskaya, T. N. Pol’shina, Yu. A. Fedorov, S. S. Mandzhieva, V. A. Chaplygin, T. V. Bauer, and M. V. Burachevskaya, “Heavy metals in the soil–plant system of the Don River estuarine region and the Taganrog Bay coast,” J. Soils Sediments 17 (5), 1474–1491 (2017). https://doi.org/10.1007/s11368-016-1381-x

    Article  Google Scholar 

  34. Proposal for a European Soil Monitoring and Assessment Framework (European Environmental Agency, Copenhagen, 2001).

  35. The State of Soil in Europe, A Contribution of the JRC to the EEA Environment State and Outlook Report–SOER 2010 (European Environment Agency, Luxembourg, 2012).

  36. V. S. Walopereis, C. Gascuel-Odoux, G. Baernie, and G. Soignet, “Spatial variability of heavy metals in soil on a one-hectare scale,” Soil Sci. 146 (2), 113–118 (1988).

    Article  Google Scholar 

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Funding

This study was supported in part by the Russian Foundation for Basic Research, project no. 16-04-00592.

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Correspondence to O. S. Bezuglova.

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Translated by D. Konyushkov

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Chernova, O.V., Bezuglova, O.S. Use of Background Concentrations of Heavy Metals for Regional Monitoring of Soil Contamination by the example of Rostov Oblast. Eurasian Soil Sc. 52, 1007–1017 (2019). https://doi.org/10.1134/S1064229319080040

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