Skip to main content
Log in

Structural transformations in zirconia under cumulative explosion conditions

  • Published:
Technical Physics Letters Aims and scope Submit manuscript

Abstract

We have studied structural transformations in nanocrystalline zirconia (ZrO2) loaded by cumulative jets generated by the explosions of charges with cone-shape linings based on the nanocrystalline ZrO2 powders. It is established that the material under such conditions can occur in a highly nonequilibrium structural state. The phenomenon of relaxation of such a nonequilibrium state upon explosion has been observed, which is terminated at room temperature for a time on the order of 1000 h. Estimation gives an anomalously low value of the apparent activation energy (∼3.5 kcal/mol) of this process

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. S. A. Gromilov, S. A. Kinelovskii, Yu. N. Popov, and Yu. A. Trishin, Fiz. Goreniya Vzryva 33(6), 127 (1997) [Combust. Explos. Shock Waves 33, 734 (1997)].

    Google Scholar 

  2. S. A. Kinelovskii and S. A. Gromilov, Fiz. Goreniya Vzryva 37(2), 135 (2001) [Combust. Explos. Shock Waves 37, 243 (2001)].

    Google Scholar 

  3. S. A. Gromilov and S. A. Kinelovskii, Zh. Strukt. Khim. 44, 486 (2003) [J. Struct. Chem. 44, 434 (2003)].

    Google Scholar 

  4. T. Cosmas, R. Wagner, and N. Claussen, J. Am. Ceram. Soc. 64(4), 72 (1981).

    Google Scholar 

  5. B. Morosin and R. A. Graham, X-ray Diffraction Line Broadening Studies on Shock-Loaded TiO2 and Al2O3, in Shock Waves in Condensed Matter, Ed. by J. R. Assay, R. A. Graham, and G. K. Straub (Elsevier Sci. Publ., 1984), pp. 355–362.

  6. S. N. Kul’kov, V. F. Nesterenko, P. V. Korolev, et al., Fiz. Goreniya Vzryva 29(6), 66 (1993) [Combust. Explos. Shock Waves 29, 728 (1993)].

    Google Scholar 

  7. B. Morosin, R. A. Graham, and J. R. Hellman, in Shock Waves in Condensed Matter, Ed. by J. R. Assay, R. A. Graham, and G. K. Straub (Elsevier Sci. Publ., 1984), pp. 383–386.

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to S. N. Kul’kov.

Additional information

Original Russian Text © S.N. Kul’kov, S.A. Kinelovskii, 2008, published in Pis’ma v Zhurnal Tekhnicheskoĭ Fiziki, 2008, Vol. 34, No. 7, pp. 7–13.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kul’kov, S.N., Kinelovskii, S.A. Structural transformations in zirconia under cumulative explosion conditions. Tech. Phys. Lett. 34, 274–277 (2008). https://doi.org/10.1134/S1063785008040020

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063785008040020

PACS numbers

Navigation