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Paramagnetic defects in manganese-doped lead tungstate

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Abstract

In manganese-doped PbWO4 crystals, low-intensity signals of triclinic clusters Mn4+-V O and Fe3+-V Pb have been revealed in addition to signals of Mn2+ tetragonal centers. The Mn4+-V O cluster is formed by a Mn4+ ion in the W6+ position, which is associated with a vacancy of the nearest neighbor O2−ion, and the Fe3+-V Pb cluster consists of a Fe3+ ion substituting for Pb2+ with a local compensation of by a lead vacancy. It has been shown that, in PbWO4: Mn, there is also a small amount of Mn4+ tetragonal centers located in the Pb2+ position with a nonlocal compensation of an excess charge.

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Authors and Affiliations

  1. Ioffe Physical-Technical Institute, Russian Academy of Sciences, Politekhnicheskaya ul. 26, St. Petersburg, 194021, Russia

    G. R. Asatryan

  2. Institute of Physics, Czech Academy of Science, Na Slovance 1999/2, Prague 8, 182 21, Czech Republic

    M. Nikl

  3. Institute of Natural Science, Ural Federal University named after the First President of Russia B.N. Yeltsin, ul. Kuibysheva 48, Yekaterinburg, 620083, Russia

    V. A. Vazhenin & A. P. Potapov

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  1. G. R. Asatryan
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  2. M. Nikl
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  4. A. P. Potapov
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Correspondence to G. R. Asatryan.

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Original Russian Text © G.R. Asatryan, M. Nikl, V.A. Vazhenin, A.P. Potapov, 2013, published in Fizika Tverdogo Tela, 2013, Vol. 55, No. 1, pp. 102–107.

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Asatryan, G.R., Nikl, M., Vazhenin, V.A. et al. Paramagnetic defects in manganese-doped lead tungstate. Phys. Solid State 55, 116–122 (2013). https://doi.org/10.1134/S106378341301006X

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