Skip to main content
SpringerLink
Log in

Synthesis, Structure, and Luminescence of a Zinc Coordination Polymer Based on Bis(4-(2'-methylimidazol)phenyl)sulfone and 4-Nitrophthalate Ligands

  • STRUCTURE OF ORGANIC COMPOUNDS
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

A zinc coordination polymer with V-shaped ligands, [L1Zn(npa)]n (L1 = bis(4-(2'-methylimidazol)phenyl)sulfone, H2npa = 4-nitrophthalic acid) has been synthesized under solvothermal conditions. The structure has been determined by single-crystal X-ray diffraction analysis and characterized by IR spectra, and elemental analyses. In crystal adjacent [Zn2(npa)2] units linked by four bridging ligands L1 form 2D layers, which are entangled between each other giving inclined interpenetration with the angle of 52.9°, thus resulting in a complicated 3D unique network. Moreover, luminescent properties of the title compound have been investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. W. Xuan, C. Zhu, Y. Liu, et al., Chem. Soc. Rev. 41, 1677 (2012).

    Article  Google Scholar 

  2. Y. Liu, W. Xuan, and Y. Cui, Adv. Mater. 22, 4112 (2010).

    Article  Google Scholar 

  3. S. L. James, Chem. Soc. Rev. 32, 276 (2003).

    Article  Google Scholar 

  4. Y. Wei, Y. Yu, and K. Wu, Cryst. Growth Des. 8, 2087 (2008).

    Article  Google Scholar 

  5. F. Luo, Y. X. Che, and J. M. Zheng, Cryst. Growth Des. 9, 1066 (2008).

    Article  Google Scholar 

  6. Y.-T. Yan, J. Liu, G.-P. Yang, et al., CrystEngComm 20, 477 (2018).

    Article  Google Scholar 

  7. X.-F. Zhang, T. Yan, T. Wang, et al., CrystEngComm 20, 570 (2018).

    Article  Google Scholar 

  8. Q.-Q. Li, Z.-Y. Chao, C.-Y. Liu, et al., Cryst. Growth Des. 18, 2784 (2018).

    Article  Google Scholar 

  9. X. Guo, Y. Yan, H. Guo, et al., Inorg. Chem. Commun. 64, 59 (2016).

    Article  ADS  Google Scholar 

  10. S. Liu, M. Guo, Y. Sun, et al., Inorg. Chim. Acta 474, 73 (2018).

    Article  ADS  Google Scholar 

  11. W. Li, X. Sun, J. Suo, et al., Z. Kristallogr.-New Cryst. Struct. 233, 65 (2018)

    Article  Google Scholar 

  12. G.-F. Wang, X. Zhang, S.-W. Sun, et al., Z. Naturforsch. 71b, 869 (2016).

    Article  Google Scholar 

  13. G.-F. Wang, X. Zhang, Z.-R. Liu, et al., Z. Naturforsch. 72b, 83 (2017).

    Article  Google Scholar 

  14. G.-F. Wang, X. Zhang, S.-W. Sun, et al., Z. Naturforsch. 72b, 257 (2017).

    Article  Google Scholar 

  15. CrysAlisPro Version 1.171.35.19 (Agilent Technologies Inc., Santa Clara, CA, USA, 2011).

  16. G. M. Sheldrick, Program for Multi-Scan Absorption Correction (Univ. of Göttingen, Göttingen, Germany, 2000).

    Google Scholar 

  17. P. T. Beurskens, G. Admiraal, G. Beurskens, et al., The DIRDIF Program System, Technical Report of the Crystallography Laboratory (Univ. of Nijmegen, Nijmegen, The Netherlands, 1992).

    Google Scholar 

  18. G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).

    Article  ADS  Google Scholar 

  19. J. E. McGarrah, Y. J. Kim, M. Hissler, et al., Inorg. Chem. 40, 4510 (2001).

    Article  Google Scholar 

  20. X. He, C. Z. Lu, and D. Q. Yuan, Inorg. Chem. 45, 5760 (2006).

    Article  Google Scholar 

  21. W. Ouellette, B. S. Hudson, and J. Zubieta, Inorg. Chem. 46, 4887 (2007).

    Article  Google Scholar 

  22. X. Shi, G. Zhu, Q. Fang, et al., Eur. J. Inorg. Chem. 2004, 185 (2004).

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was financially supported by the Young Teacher Starting-up Research of Yuncheng University (YQ-2015007) and Applied Research Projects of Yuncheng University (no. CY-2018019).

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Yuncheng University, 044000, Yuncheng, China

    Gao-Feng Wang &  Shu-Wen Sun

Authors
  1. Gao-Feng Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shu-Wen Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Gao-Feng Wang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gao-Feng Wang, Shu-Wen Sun Synthesis, Structure, and Luminescence of a Zinc Coordination Polymer Based on Bis(4-(2'-methylimidazol)phenyl)sulfone and 4-Nitrophthalate Ligands. Crystallogr. Rep. 64, 1075–1079 (2019). https://doi.org/10.1134/S1063774519070265

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774519070265

Search

Navigation