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Assessing the Efficiency of Rapid Methods for Evaluating Selectivity and Analytical Signal Strength in Various Fluorescent Phases

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Abstract

The results of evaluating the adsorption and fluorescent properties of azolotriazine compounds and phases based on cadmium sulfide quantum dots in vapors of volatile organic compounds (biomarkers of living systems) are considered. The adsorption properties of phases based on organic dyes and encapsulated semiconductors towards vapors of alcohols, ketones, amines, acids, ammonia, and aldehydes are investigated using direct high-sensitivity piezoelectric quartz microweighing. The spectral properties and their variations in analyte vapors are investigated using various spectroscopy methods (absorption, photoluminescence). The research results are compared, and the potential for optimizing this stage is assessed. It is proposed to evaluate the consistency of methods for predicting changes in fluorescent properties in test systems for volatile organic compounds using the Kendall coefficient of concordance, W. The highest level of agreement (W = 0.89) was observed between the methods of spectrofluorimetry and direct vapor microweighing upon adsorption on phases being potential fillers of test systems. A correlation between the results obtained by different fluorescence methods (visual plate test systems and fluorimetry of phases on paper substrates) is 0.80, which confirms a high degree of consistency in assessments using them in the degree of interaction between the analytes and organic, combined fluorochromes. The methods closely related in the nature of the analytical response do not exhibit better agreement than the method of direct vapor microweighing on microphases of fluorimetric reagents of different nature (cadmium sulfide quantum dots/chitosan, organic azolotriazine compounds, mixed phases). This, in turn, enables the selection of simpler, more available, and more rapid methods and means of analysis in routine experiments.

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Funding

The synthesis and investigation of organic reagents were supported by a grant of the President of the Russian Federation for the State Support of Young Russian Scientists—Candidates of Sciences (project no. MK-4978.2022.1.3). The synthesis and investigation of cadmium sulfide quantum dots and phases based on it were supported by the Russian Science Foundation (grant no. 23-23-00609).

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Authors and Affiliations

  1. Voronezh State University of Engineering Technology, 394036, Voronezh, Russia

    T. A. Kuchmenko & R. U. Umarkhanov

  2. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 119334, Moscow, Russia

    T. A. Kuchmenko & V. V. Yagov

  3. Burdenko State Medical University, 394036, Voronezh, Russia

    D. Yu. Vandyshev & I. V. Ledneva

Authors
  1. T. A. Kuchmenko
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  2. D. Yu. Vandyshev
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  3. V. V. Yagov
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  4. R. U. Umarkhanov
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  5. I. V. Ledneva
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Correspondence to T. A. Kuchmenko.

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Translated by O. Zhukova

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Kuchmenko, T.A., Vandyshev, D.Y., Yagov, V.V. et al. Assessing the Efficiency of Rapid Methods for Evaluating Selectivity and Analytical Signal Strength in Various Fluorescent Phases. J Anal Chem 79, 614–627 (2024). https://doi.org/10.1134/S106193482405006X

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  • DOI: https://doi.org/10.1134/S106193482405006X

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