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Study of the transfer of aminoglycoside antibiotics through the phase boundary water/o-nitrophenyl octyl ether by voltammetry at the interface of two immiscible electrolyte solutions

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Abstract

The transfer of aminoglycoside antibiotics streptomycin, kanamycin, and gentamycin induced by dibenzo-18-crown-6 is studied by voltammetry at the interface of two immiscible electrolyte solutions (ITIES). An assumption about the 1: 1 stoichiometry of the complexes formed is formulated. The method is proposed for use in the analysis of kanamycin and streptomycin in aqueous solutions. The optimal conditions of analysis of these aminoglycosides are found, the detection limits are 8.0 × 10−5 M for streptomycin and 2.0 × 10−4 M for kanamycin. The selectivity of streptomycin analysis by ITIES voltammetry in presence of potassium and sodium is studied. An amperometric ion-selective electrode is developed for the determination of streptomycin in drug formulations with a detection limit of 9.0 × 10−5 M.

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Authors and Affiliations

  1. Faculty of Natural Sciences, Mendeleev Russian University of Chemistry and Technology, Miusskaya pl. 9, Moscow, 125047, Russia

    E. V. Vladimirova, A. A. Dunaeva, O. M. Petrukhin & E. V. Shipulo

Authors
  1. E. V. Vladimirova
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  2. A. A. Dunaeva
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  3. O. M. Petrukhin
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  4. E. V. Shipulo
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Additional information

Original Russian Text © E.V. Vladimirova, A.A. Dunaeva, O.M. Petrukhin, E.V. Shipulo, 2013, published in Zhurnal Analiticheskoi Khimii, 2013, Vol. 68, No. 3, pp. 272–279.

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Vladimirova, E.V., Dunaeva, A.A., Petrukhin, O.M. et al. Study of the transfer of aminoglycoside antibiotics through the phase boundary water/o-nitrophenyl octyl ether by voltammetry at the interface of two immiscible electrolyte solutions. J Anal Chem 68, 253–260 (2013). https://doi.org/10.1134/S106193481303012X

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  • DOI: https://doi.org/10.1134/S106193481303012X

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