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Dilational rheology of spread and adsorbed layers of silica nanoparticles at the liquid-gas interface

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Abstract

This short review is devoted to recent achievements in studies of the dilational surface rheological properties of the systems containing complexes of silica nanoparticles with conventional surfactants. It is shown that there is a surfactant concentration range where the dynamic surface elasticity reaches extremely high values up to 1000 mN/m. This result can explain the formation of very stable foams and emulsions containing nanoparticles. In some surfactant concentration ranges the adsorption layer is characterized by a non-linear response to small compressions or expansions of the liquid surface. Possible causes of this behavior and the mechanism of main relaxation processes are briefly discussed.

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Authors and Affiliations

  1. Department of Colloid Chemistry, St. Petersburg State University, Universitetsky pr. 26, 198504, St. Petersburg, Russia

    B. A. Noskov & P. A. Yazhgur

  2. CNR—Institute for Energetics and Interphases—Genoa Dept., via De Marini 6, 16149, Genoa, Italy

    L. Liggieri & F. Ravera

  3. Chemical Engineering Department, National Taiwan University of Science and Technology, 43 Keelung Road, Section 4, Taipei, 106, Taiwan

    S. -Y. Lin

  4. Dipartimento di Chimica Organica, Universita degli Studi di Firenze, Via della Lastruccia 13, 50019, Sesto Fiorentino, Firenze, Italy

    G. Loglio

  5. MPI für Kolloid- und Grenzfl@achenforschung, Wissenschaftspark Golm, D-14424, Golm, Germany

    R. Miller

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  1. B. A. Noskov
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  2. P. A. Yazhgur
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  7. F. Ravera
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Noskov, B.A., Yazhgur, P.A., Liggieri, L. et al. Dilational rheology of spread and adsorbed layers of silica nanoparticles at the liquid-gas interface. Colloid J 76, 127–138 (2014). https://doi.org/10.1134/S1061933X14020057

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  • DOI: https://doi.org/10.1134/S1061933X14020057

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