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Crystal Structure and Orbital Ordering in BiMnO3 + δ (0 < δ ≤ 0.14) Ceramics

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Abstract

The crystal structure of BiMnO3 + δ is studied as a function of the nominal oxygen content using X-ray synchrotron diffraction. It is found that an increase in the nominal oxygen-ion concentration leads to a series of phase transitions from the monoclinic (C2/c) to another monoclinic phase (P21/c) and then to the orthorhombic structure Pnma through the formation of a two-phase structural state. The indicated sequence of the phase transitions is accompanied by gradual destruction of the orbital ordering formed by the orbitals of Mn3+ ions, which is caused by the nonuniform distribution of vacancies of manganese ions in the B positions of the perovskite lattice.

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ACKNOWLEDGMENTS

We thank the Helmholtz-Zentrum Berlin für Materialien und Energie for the synchrotron studies.

Funding

The research was carried out with the support of the Russian Foundation for Basic Research (project no. 20-52-00023) and the Belarusian Republican Foundation for Basic Research (project no. T20P-121) within the framework of the State assignment of the Ministry of Higher Education and Science, project FZWM-2020-0008.

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Authors and Affiliations

  1. Joint Institute for Nuclear Research, 141980, Dubna, Moscow oblast, Russia

    V. V. Sikolenko & B. N. Savenko

  2. Scientific-Practical Materials Research Centre, National Academy of Sciences of Belarus, 220072, Minsk, Belarus

    A. N. Chobot, M. V. Bushinsky, D. V. Zheludkevich, S. I. Latushko & D. V. Karpinsky

  3. Belarusian State Agrarian Technical University, 220023, Minsk, Belarus

    G. M. Chobot

  4. Karlsruhe Institute of Technology, 76131, Karlsruhe, Germany

    V. V. Sikolenko

  5. Scientific and Educational Center “Functional Nanomaterials”, Kant Baltic Federal University, 236016, Kaliningrad, Russia

    V. V. Sikolenko

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  1. V. V. Sikolenko
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  2. A. N. Chobot
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  3. M. V. Bushinsky
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Correspondence to V. V. Sikolenko or A. N. Chobot.

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Sikolenko, V.V., Chobot, A.N., Bushinsky, M.V. et al. Crystal Structure and Orbital Ordering in BiMnO3 + δ (0 < δ ≤ 0.14) Ceramics. J. Surf. Investig. 16, 96–100 (2022). https://doi.org/10.1134/S1027451022010335

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  • DOI: https://doi.org/10.1134/S1027451022010335

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