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Oxygen isotope exchange between the gas-phase and the electrochemical cell O2, Pt | YSZ | Pt, O2 under conditions of applied potential difference

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Abstract

The kinetics of oxygen isotope exchange between gas-phase oxygen and the electrochemical cell O2, Pt | ZrO2 + 10 mol % Y2O3 (YSZ) | Pt, O2 with applied potential difference (ΔU = ±1.2 V) is studied in the temperature range of 600–800°С and the oxygen pressure interval of 3–13 kPa. An original design of a vacuum electrochemical cell with the separated gas space is put forward for studying how the potential difference on the electrochemical cell influences the kinetics of interaction of gas-phase oxygen with the gas electrode O2, Pt | YSZ in the electrochemical cell. It is shown that the oxygen interphase exchange rate is the higher the more negative the charge on the electrode studied; moreover, the mechanism of gas-phase oxygen exchange with the gas electrode O2, Pt | YSZ in the electrochemical cell depends fundamentally on the electrode charge sign. The possible reasons for the revealed differences are discussed; the corresponding models are proposed.

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Authors and Affiliations

  1. Institute of High Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620137, Russia

    A. V. Khodimchuk, M. V. Anan’ev, V. A. Eremin, E. S. Tropin, A. S. Farlenkov, N. M. Porotnikova, E. Kh. Kurumchin & D. I. Bronin

  2. Ural Federal University Named after the First President of Russia B.N. Yeltsin, Yekaterinburg, 620000, Russia

    A. V. Khodimchuk, M. V. Anan’ev, V. A. Eremin, E. S. Tropin, A. S. Farlenkov, N. M. Porotnikova & D. I. Bronin

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  1. A. V. Khodimchuk
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  2. M. V. Anan’ev
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  3. V. A. Eremin
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  4. E. S. Tropin
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  5. A. S. Farlenkov
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  6. N. M. Porotnikova
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  7. E. Kh. Kurumchin
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  8. D. I. Bronin
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Correspondence to A. V. Khodimchuk.

Additional information

Published on the basis of a report delivered at the 13th International Meeting “Fundamental Problems of Solid State Ionics,” Chernogolovka, 2016.

Original Russian Text © A.V. Khodimchuk, M.V. Anan’ev, V.A. Eremin, E.S. Tropin, A.S. Farlenkov, N.M. Porotnikova, E.Kh. Kurumchin, D.I. Bronin, 2017, published in Elektrokhimiya, 2017, Vol. 53, No. 8, pp. 940–949.

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Khodimchuk, A.V., Anan’ev, M.V., Eremin, V.A. et al. Oxygen isotope exchange between the gas-phase and the electrochemical cell O2, Pt | YSZ | Pt, O2 under conditions of applied potential difference. Russ J Electrochem 53, 838–845 (2017). https://doi.org/10.1134/S1023193517080109

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  • DOI: https://doi.org/10.1134/S1023193517080109

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