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Removal of Cerium from Wastewater Based on Polymer-Enhanced Ultrafiltration Technology through Polyethersulfone-g-Poly(N-vinyl-2-pyrrolidone) Modified Membrane

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Abstract

In this paper, we prepared the modified polyethersulfone-g-poly(N-vinyl-2-pyrrolidone) ultrafiltration membrane by gamma-ray irradiation in a homogenous solution. The cross-section and surface micromorphology of the membrane prepared with different polyethersulfone mass fractions were analyzed by scanning electron microscope. Meanwhile, based on polymer-enhanced ultrafiltration technology combined with our self-made membrane performance testing system, the effects of polymer/metal ion mass ratio and pH value of the aqueous solution on membrane permeation flux and Ce3+ rejection rate were analyzed. According to these experimental results, a reasonable complexation reaction between polyethyleneimine and Ce3+, and the mechanism of the membrane’s separation of Ce3+ from an aqueous solution were proposed.

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Funding

This work was supported financially by the science and technology research project of the Chongqing Education Commission (Project no. KJQN202003103), the open projects of the CAS key laboratory of interfacial physics and technology (nos. CASKL-IPT2002 and CASKL-IPT2004), School-level subject of Chongqing College of Electronic Engineering (Project no. XJZK202107).

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Correspondence to Jihao Li or Faliang Xu.

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Kai Fan, Zhou, G., Gao, C. et al. Removal of Cerium from Wastewater Based on Polymer-Enhanced Ultrafiltration Technology through Polyethersulfone-g-Poly(N-vinyl-2-pyrrolidone) Modified Membrane. Polym. Sci. Ser. A 64, 541–548 (2022). https://doi.org/10.1134/S0965545X22700195

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  • DOI: https://doi.org/10.1134/S0965545X22700195

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