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Optical and hydrodynamic properties of solutions of copolymers of N,N-dimethylaminoethyl methacrylate and 2-deoxy-2-methacrylamido-D-glucose that contain silver particles

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Abstract

Ag0 nanoparticles are prepared via the reduction of silver ions by copolymers of N,N-dimethylaminoethyl methacrylate and 2-deoxy-2-methacrylamido-D-glucose of various compositions in water at room temperature. It is found that an insignificant part of the macromolecules is involved in the reduction of Ag+ to Ag0 and stabilization of the resulting nanoparticles. As shown by flow-birefringence studies, the optical properties of solutions of stabilized silver nanoparticles change abruptly relative to the optical properties of the solutions of the initial copolymers.

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References

  1. B. G. Ershov, Ross. Khim. Zh. 45(3), 20 (2001).

    CAS  Google Scholar 

  2. Yu. A. Krutyakov, A. A. Kudrinskiy, A. Yu. Olenin, and G. V. Lisichkin, Russ. Chem. Rev. 77(3), 233 (2008).

    Article  CAS  Google Scholar 

  3. M. Valodkar, A. Bhadoria, J. Pohnerkar, M. Mohan, S. Thakore, Carbohydr. Res. 345(12), 1767 (2010).

    Article  CAS  Google Scholar 

  4. V. V. Kopeikin and E. F. Panarin, Dokl. Chem. 380(4–6), 277 (2001).

    Article  Google Scholar 

  5. H. Sun, Z. Gao, L. Yang, L. Gao, X. Lv, Colloid Polym. Sci. 288(18), 1713 (2010).

    Article  CAS  Google Scholar 

  6. J. A. Reyes-Esqueda, C. Torres-Torres, J. C. Cheang-Wong, A. Crespo-Sosa, L. Rodriguez-Fernandez, C. Noguez, Al. Oliver, Opt. Express 16(2), 710 (2008).

    Article  CAS  Google Scholar 

  7. J. A. Reyes-Esqueda, V. Iglesias, H. G. Silva-Pereyra, C. Torres-Torres, A. L. Santiago-Ramirez, J. C. Cheang-Wong, A. Crespo-Sosa, L. Rodriguez-Fernandez, A. Lopez-Suarez, A. Oliver, Opt. Express 17(15), 12849 (2009).

    Article  CAS  Google Scholar 

  8. S. Camelio, D. Babonneau, D. Lantiat, and F. Pailloux, Phys. Rev. 80(15), 155434 (2009).

    Article  Google Scholar 

  9. N. Kunzner, D. Kovalev, J. Diener, E. Gross, V. Yu. Timoshenko, G. Polisski, F. Koch, M. Fujii, Phys. Rev. 26(16), 1265 (2001).

    CAS  Google Scholar 

  10. Y. Chang, W. Li, and Y. Jiang, Phys. Lett. A 376(34), 2314 (2012).

    Article  CAS  Google Scholar 

  11. S. A. Khan, T. Senapati, P. Bonifassi, Z. Fan, A. K. Singh, A. Neeley, D. G. Hill, P. C. Ray, Chem. Phys. Lett. 512(1–3), 92 (2011).

    Article  CAS  Google Scholar 

  12. L. Li, X. Wang, W. F. Sun, and Q. Q. Lei, Acta Phys. Sin., No. 10 (2013).

    Google Scholar 

  13. Yo. Sun, D. Wang, J. Gao, Z. Sheng, Q. Zhang, J. Appl. Polym. Sci. 103(6), 3701 (2007).

    Article  CAS  Google Scholar 

  14. A. G. El-Shamy, W. Attia, K. M. Abd El-Kader, J. Alloys Compd. 590, 309 (2014).

    Article  CAS  Google Scholar 

  15. A. K. M. Maidul Islam and M. Mukherjee, J. Exp. Nanosci. 6(6), 596 (2011).

    Article  CAS  Google Scholar 

  16. D. Castonguay and A. K. Kakkar, Adv. Colloid Interface Sci. 160(1) (2010).

    Google Scholar 

  17. P. R. Gopalan, Int. J. Nanosci. 9(5), 487 (2010).

    Article  CAS  Google Scholar 

  18. M. M. Stevanovic, S. D. Skapin, I. Bracko, M. Milenkovic, J. Petkovic, M. Filipic, D. P. Uskokovic, Polymer 53(14), 2818 (2012).

    Article  CAS  Google Scholar 

  19. A. D. Pomogailo, Ross. Khim. Zh. 46(5), 64 (2002).

    CAS  Google Scholar 

  20. T. N. Nekrasova, Yu. I. Zolotova, O. V. Nazarova, E. I. Suvorova, A. K. Sirotkin, Yu. G. Baklagina, E. V. Didenko, V. D. Pautov, E. F. Panarin, Dokl. Chem. 446(2), 212 (2012).

    Article  CAS  Google Scholar 

  21. Photon Correlation Spectroscopy and Velocimetry, Ed. by H. Z. Cummins and E. R. Pike (Plenum Press, New York, 1977).

    Google Scholar 

  22. B. J. Berne and R. Pecora, Dynamic Light Scattering: With Applications to Chemistry, Biology and Physics (Dover Publ., Courier, 2000).

    Google Scholar 

  23. E. A. Litmanovich and E. M. Ivleva, Polym. Sci., Ser. A 52(6), 920 (2010).

    Article  Google Scholar 

  24. N. V. Tsvetkov, Rigid Chain Polymers (Plenum Press, New York, 1989).

    Google Scholar 

  25. V. N. Tsvetkov and S. V. Bushin, J. Polym. Sci., Polym. Chem. Ed., No. 11, D. 3447 (1984).

    Google Scholar 

  26. L. N. Andreeva, M. A. Bezrukova, S. V. Bushin, T. N. Nekrasova, R. T. Imanbaev, V. D. Pautov, Yu. I. Zolotova, O. V. Nazarova, E. F. Panarin, Polym. Sci., Ser. A 56(4), 405 (2014).

    Article  CAS  Google Scholar 

  27. V. Tsvetkov and L. Andreeva, Adv. Polym. Sci. 39, 95 (1981).

    Article  CAS  Google Scholar 

  28. D. J. Alner and R. C. Lansbury, J. Chem. Soc., 3169 (1961).

    Google Scholar 

  29. M. Sedlák, J. Chem. Phys. 105(22), 8 (1996).

    Article  Google Scholar 

  30. E. F. Panarin, G. M. Pavlov, and Yu. G. Santuryan, Khim.-Farm. Zh. 25(3), 68 (1991).

    CAS  Google Scholar 

  31. H. G. Elias, Macromolecules, Structure and Properties (Plenum Press, New York, London, 1977).

    Google Scholar 

  32. C. F. Bohren and D. R. Huffman, Absorption and Scattering of Light by Small Particles (Wiley, New York, 1998).

    Book  Google Scholar 

Download references

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Correspondence to O. V. Nazarova.

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Original Russian Text © T.N. Nekrasova, L.N. Andreeva, A.A. Lezov, M.A. Bezrukova, O.V. Nazarova, Yu.I. Zolotova, N.V. Tsvetkov, E.F. Panarin, 2015, published in Vysokomolekulyarnye Soedineniya. Ser. A, 2015, Vol. 57, No. 2, pp. 99–111.

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Nekrasova, T.N., Andreeva, L.N., Lezov, A.A. et al. Optical and hydrodynamic properties of solutions of copolymers of N,N-dimethylaminoethyl methacrylate and 2-deoxy-2-methacrylamido-D-glucose that contain silver particles. Polym. Sci. Ser. A 57, 103–114 (2015). https://doi.org/10.1134/S0965545X15020121

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  • DOI: https://doi.org/10.1134/S0965545X15020121

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