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Properties of carboxymethyl cellulose aqueous solutions with nanoparticle additives and the related composite films

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Abstract

The rheological properties of carboxymethyl cellulose aqueous solutions containing small amounts of purified montmorillonite and bentonite nanoparticles are studied. The viscosity of mixed solutions decreases after addition of 1 wt % nanoparticles. X-ray diffraction analysis shows that the films contain nanoparticles in the exfoliated state. An examination of the FTIR spectra of composite films suggests a shift in the absorption band due to Si-O groups. This phenomenon may be explained both by a change in the permittivity of the nanoparticle environment and by the formation of hydrogen bonds between Si-O groups and functional groups of cellulose ether. It is shown that the content of the added nanoparticles influences the mechanical characteristics of the films prepared from the systems of interest.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bolshoi pr. 31, St. Petersburg, 199004, Russia

    A. M. Bochek, N. M. Zabivalova, V. E. Yudin, I. V. Gofman, V. K. Lavrent’ev, B. Z. Volchek, E. N. Vlasova & I. V. Abalov

  2. St. Petersburg State Technological University of Plant Polymers, ul. Ivana Chernykh 4, St. Petersburg, 198095, Russia

    N. G. Brusilovskaya & I. I. Osovskaya

Authors
  1. A. M. Bochek
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  2. N. M. Zabivalova
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  3. V. E. Yudin
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  4. I. V. Gofman
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  5. V. K. Lavrent’ev
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  6. B. Z. Volchek
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  7. E. N. Vlasova
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  8. I. V. Abalov
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  9. N. G. Brusilovskaya
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  10. I. I. Osovskaya
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Correspondence to A. M. Bochek.

Additional information

Original Russian Text © A.M. Bochek, N.M. Zabivalova, V.E. Yudin, I.V. Gofman, V.K. Lavrent’ev, B.Z. Volchek, E.N. Vlasova, I.V. Abalov, N.G. Brusilovskaya, I.I. Osovskaya, 2011, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2011, Vol. 53, No. 12, pp. 2085–2093.

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Bochek, A.M., Zabivalova, N.M., Yudin, V.E. et al. Properties of carboxymethyl cellulose aqueous solutions with nanoparticle additives and the related composite films. Polym. Sci. Ser. A 53, 1167–1174 (2011). https://doi.org/10.1134/S0965545X11120029

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  • DOI: https://doi.org/10.1134/S0965545X11120029

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