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Synthesis and structural and conformational properties of hybrid polymers of styrene with perfluorinated compounds of germanium

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Abstract

Polymers of various structures, namely, the model PS with pentafluorophenyl groups, the linear-dendrite perfluorinated polyphenylenegermane-polystyrene, and diblock copolymer polystyrene-Ge(C6F5)2-polystyrene, have been prepared by radical polymerization and activated copolycondensation. The polymers have been studied in dilute solutions by GPC, static and dynamic light scattering, and viscometry. The addition of a bis(pentafluorophenyl group) to the ends of a PS chain facilitates the development of supramolecular structures in solutions of hybrid systems. If the fluorinated group is incorporated at the center of the polymer chain, no associative phenomena are observed, because of its screening by the molecular coil.

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Authors and Affiliations

  1. Lobachevskii Nizhni Novgorod State University, pr. Gagarina 23/2, Nizhni Novgorod, 603950, Russia

    O. G. Zakharova & Yu. D. Semchikov

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31, St. Petersburg, 199004, Russia

    E. V. Tarasova, M. A. Simonova & A. P. Filippov

Authors
  1. O. G. Zakharova
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  2. E. V. Tarasova
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  3. M. A. Simonova
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  4. Yu. D. Semchikov
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  5. A. P. Filippov
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Corresponding author

Correspondence to A. P. Filippov.

Additional information

Original Russian Text © O.G. Zakharova, E.V. Tarasova, M.A. Simonova, Yu.D. Semchikov, A.P. Filippov, 2009, published in Vysokomolekulyarnye Soedineniya, Ser. A, 2009, Vol. 51, No. 5, pp. 768–774.

This work was supported by the Russian Foundation for Basic Research, project nos. 05-03-33152, 06-03-32872, and 08-03-00421.

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Zakharova, O.G., Tarasova, E.V., Simonova, M.A. et al. Synthesis and structural and conformational properties of hybrid polymers of styrene with perfluorinated compounds of germanium. Polym. Sci. Ser. A 51, 512–517 (2009). https://doi.org/10.1134/S0965545X09050046

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  • DOI: https://doi.org/10.1134/S0965545X09050046

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