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Physicochemical Characteristics and Catalytic Activity of Composite Materials Based on Mixed Oxides MTiO3/TiO2 (М = Co, Ni) in 1,2-Dihydroxybenzene Photodegradation Reactions in Aqueous Solutions

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Abstract

Mixed cobalt and nickel oxides MTiO3/TiO2 (M = Co2+, Ni2+) are synthesized. Organometallic complexes of titanium tetrabutylate Ti(OBu)4 with 1,2-dihydroxybenzene and nitrate hydrates of corresponding metals (M) synthesized under conditions of the modified sol-gel process are used as precursors. The synthesized samples are characterized by field-emission scanning electron microscopy, energy-dispersive X-ray analysis, diffuse reflectance spectroscopy, dispersive X-ray radiation analysis, X-ray diffraction, and low-temperature nitrogen adsorption. The photocatalytic activity of the samples is tested in the ultraviolet spectral range (200 nm < λ < 400 nm) in the photodegradation of 1,2-dihydroxybenzene (catechol) in aqueous solutions.

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REFERENCES

  1. M. Bilal, T. Rasheed, H. M. N. Iqbal, C. Li, and X. Zhang, Chem. Eng. Res. Des. 129, 384 (2018). https://doi.org/10.1016/j.cherd.2017.11.040

    Article  CAS  Google Scholar 

  2. P. Sathishkumar, M. R. Viswanathan, and S. Anandan, Renewable Sustainable Energy Rev. 55, 426 (2016). https://doi.org/10.1016/j.rser.2015.10.139

    Article  CAS  Google Scholar 

  3. P. V. Kamat, Chem. Rev. 93, 267 (1993). https://doi.org/10.1021/cr00017a013

    Article  CAS  Google Scholar 

  4. A. Mills and S. Le Hunte, J. Photochem. Photobiol. A 108 (1), 1 (1997). https://doi.org/10.1016/S1010-6030(97)00118-4

    Article  CAS  Google Scholar 

  5. M. R. Hoffmann, T. Scot, C. Wonyong, D. Bahnemann, and W. B. Detlef, Chem. Rev. 95, 69 (1995). https://doi.org/10.1021/cr00033a004

    Article  CAS  Google Scholar 

  6. P. A. Cox, Transition Metal Oxides: An Introduction to Their Electronic Structure and Properties (Oxford Univ. Press, 2010), pp. 1–284.

    Google Scholar 

  7. M. N. Danilova, E. M. Kasatkin, A. I. Pylinina, I. G. Bratchikova, I. I. Mikhalenko, and V. D. Yagodovskii, Kinet. Catal. 56 (4), 476 (2015). https://doi.org/10.1134/S0023158415040060

    Article  CAS  Google Scholar 

  8. Y. Absalan, I. Bratchikova, and O. V. Kovalchukova, Environ. Nanotechnol. Monit. Manage. 8, 244 (2017). https://doi.org/10.1016/j.enmm.2017.08.001

    Article  Google Scholar 

  9. I. I. Mikhalenko, E. I. Povarova, and A. I. Pylinina, Rus. J. Phys. Chem. A 90 (4), 771 (2016). https://doi.org/10.1134/S0036024416040221

    Article  CAS  Google Scholar 

  10. D. Gumy, S. A. Giraldo, J. Rengifo, and C. Pulgarin, Appl. Catal., B 78 (1–2), 19 (2008). https://doi.org/10.1016/j.apcatb.2007.08.007

    Article  CAS  Google Scholar 

  11. A. Ortiz-Gomez, B. Serrano-Rosales, M. Salaices, and H. de Lasa, Ind. Eng. Chem. Res. 46 (23), 7394 (2007). https://doi.org/10.1021/ie0611960

    Article  CAS  Google Scholar 

  12. S. W. Lam, K. Chiang, and T. M. Lim, Appl. Catal., B 72 (3-4), 363 (2007). https://doi.org/10.1016/j.apcatb.2006.11.019

    Article  CAS  Google Scholar 

  13. Y. Absalan, I. Bratchikova, N. Lobanov, and O. V. Kovalchukova, J. Mater. Sci.: Mater. Electron. 28 (23), 18207 (2017). https://doi.org/10.1007/s10854-017-7769-6

    Article  CAS  Google Scholar 

  14. Y. Absalan, E. A. Fortalnova, N. N. Lobanov, E. V. Dobrokhotova, and O. V. Kovalchukova, J. Organomet. Chem. 859, 801 (2018). https://doi.org/10.1016/j.jorganchem.2018.02.002

    Article  CAS  Google Scholar 

  15. P. Thompson, D. E. Cox, and J. B. Hastings, J. Appl. Crystallogr. 20, 79 (1987). https://doi.org/10.1107/S0021889887087090

    Article  CAS  Google Scholar 

  16. G. K. Williamson and W. H. Hall, Acta Metall. 1, 22 (1953). https://doi.org/10.1016/0001-6160(53)90006-6

    Article  CAS  Google Scholar 

  17. H. P. Klug and L. E. Alexander, X-Ray Diffraction Procedures: for Polycrystalline and Amorphous Materials (John Wiley and Sons, New York, 1974). https://doi.org/10.1002/bbpc.19750790622

    Google Scholar 

  18. B. D. Cullity, Elements of X-ray Diffraction (Addison-Wesley, Reading, MA, 1978), 531 p.

    Google Scholar 

  19. Y.-J. Lin, Y.-H. Chang, W.-D. Yang, and B.-S. Tsai, J. Non-Cryst. Solids 352 (8), 789 (2006). https://doi.org/10.1016/j.jnoncrysol.2006.02.001

    Article  CAS  Google Scholar 

  20. S. Lowell and J. E. Shields, Powder Surface Area and Porosity (Chapman and Hall, London, 1998), 242 p.

    Google Scholar 

  21. S. Gregg and K. Sing, Adsorption, Surface Area, and Porosity (Academic, New York, 1982).

    Google Scholar 

  22. K. J. Vajidar, D. H. Chen, J. L. Gossage, K. Li, X. Ye, G. Gadiyar, and B. Ardoin, Chem. Eng. Technol. 30 (4), 474 (2007). https://doi.org/10.1002/ceat.200600194

    Article  CAS  Google Scholar 

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Funding

This study was supported by the Ministry of Higher Education and Science of the Russian Federation (project no. 02, А03.21.0008). Preparation of this publication was supported by the Program 5-100 of the Peoples’ Friendship University of Russia.

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Authors and Affiliations

  1. Peoples’ Friendship University of Russia, 117198, Moscow, Russia

    Ya. Absalan, N. Yu. Isaeva, I. G. Bratchikova, O. V. Koval’chukova & A. G. Cherednichenko

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  1. Ya. Absalan
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  2. N. Yu. Isaeva
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  3. I. G. Bratchikova
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  4. O. V. Koval’chukova
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  5. A. G. Cherednichenko
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Correspondence to I. G. Bratchikova.

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CONFLICT OF INTEREST

The authors declare that there is no conflict of interest to be disclosed in this paper.

ADDITIONAL INFORMATION

Ya. Absalan, ORCID: https://orcid.org/0000-0003-2738-9645

N.Yu. Isaeva, ORCID: https://orcid.org/0000-0003-3282-4752

I.G. Bratchikova, ORCID: https://orcid.org/0000-0002-1392-6051

O.V. Koval’chukova, ORCID: https://orcid.org/0000-0002-6684-5829

A.G. Cherednichenko, ORCID: https://orcid.org/ 0000-0001-5729-9566

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Translated by T. Soboleva

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Absalan, Y., Isaeva, N.Y., Bratchikova, I.G. et al. Physicochemical Characteristics and Catalytic Activity of Composite Materials Based on Mixed Oxides MTiO3/TiO2 (М = Co, Ni) in 1,2-Dihydroxybenzene Photodegradation Reactions in Aqueous Solutions. Pet. Chem. 60, 557–562 (2020). https://doi.org/10.1134/S0965544120050011

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