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Chemistry of Dimethyl Ether: Catalytic Synthesis of 1,3-Butadiene

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Abstract

Catalytic synthesis of 1,3-butadiene from dimethyl ether (DME) has been carried out for the first time. It has been established that 1,3-butadiene forms via three possible routes of reactions between DME conversion products: by reaction of propylene with formaldehyde according to the Prins condensation mechanism, by DME isomerization of to ethanol followed by its conversion to 1,3-butadiene through acetaldehyde, and by dehydrogenation of butylenes.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, 119991, Russia

    S. N. Khadzhiev, A. L. Maksimov, V. F. Tret’yakov, R. M. Talyshinskii & A. M. Ilolov

Authors
  1. S. N. Khadzhiev
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  2. A. L. Maksimov
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  3. V. F. Tret’yakov
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  4. R. M. Talyshinskii
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  5. A. M. Ilolov
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Corresponding author

Correspondence to R. M. Talyshinskii.

Additional information

Original Russian Text © S.N. Khadzhiev, A.L. Maksimov, V.F. Tret’yakov, R.M. Talyshinskii, A.M. Ilolov, 2018, published in Neftekhimiya, 2018, Vol. 58, No. 4.

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Khadzhiev, S.N., Maksimov, A.L., Tret’yakov, V.F. et al. Chemistry of Dimethyl Ether: Catalytic Synthesis of 1,3-Butadiene. Pet. Chem. 58, 613–621 (2018). https://doi.org/10.1134/S096554411808011X

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  • DOI: https://doi.org/10.1134/S096554411808011X

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