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Features of the Kinetics and Mechanism of Stearic Acid Decarbonylation in the Presence of a Silica Gel-Supported Nickel Sulfide Catalyst

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Abstract

The substitution of silica gel for γ-Al2O3 to be used as a support for a nickel sulfide catalyst for stearic acid decarbonylation leads to a significant increase in the catalyst activity and a slight improvement of the heptadecene selectivity. Comparison with the γ-Al2O3-supported catalyst has been made in terms of the kinetic model based on experimental data. An increase in the catalyst activity is attributed to a decrease in the strength of the active site–reactant adsorption complexes on the basis of the Sabatier–Balandin principle. Relationships between the features of the reaction mechanism, the acidity of the support, and the nanoparticle size of the active substance have been discussed.

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References

  1. A. S. Berenblyum, V. Ya. Danyushevsky, P. S. Kuznetsov, et al., Pet. Chem. 56, 663 (2016).

    Article  CAS  Google Scholar 

  2. E. A. Katsman, V. Ya. Danyushevsky, P. S. Kuznetsov, et al., Kinet. Catal. 58, 147 (2017).

    Article  CAS  Google Scholar 

  3. V. Ya. Danyushevsky, P. S. Kuznetsov, E. A. Katsman, et al., Russ. Chem. Bull. 66, 463 (2017).

    Article  CAS  Google Scholar 

  4. N. A. Grosso-Giordano, T. R. Eaton, Z. Bo, et al., Appl. Catal., B 192, 93 (2016).

    Article  CAS  Google Scholar 

  5. O. N. Tsvetkov, Poly-α-olefin Oils: Chemistry, Technology, and Applications (Tekhnika, Moscow, 2006) [in Russian].

    Google Scholar 

  6. V. G. Gorskii, E. A. Katsman, F. D. Klebanova, and A. A. Grigor’ev, Theor. Exp. Chem. 23, 181 (1987).

    Article  Google Scholar 

  7. N. M. Emanuel and D. G. Knorre, Chemical Kinetics (Vyssh. Shkola, Moscow, 1984), 4th Ed. [in Russian].

    Google Scholar 

  8. Concepts of Modern Catalysis and Kinetics, Ed. by I. Chorkendorff and J. W. Niemantsverdriet (Wiley–VCH, Weinheim, 2007), 2nd Ed.

  9. O. V. Krylov, Heterogeneous Catalysis (Akademkniga, Moscow, 2004) [in Russian].

    Google Scholar 

  10. V. I. Bukhtiyarov and M. G. Slinko, Russ. Chem. Rev. 70, 147 (2001).

    Article  CAS  Google Scholar 

  11. Nanomaterials in Catalysis, Ed. by Ph. Serp and K. Philippot (Wiley–VCH, Weinheim, 2013).

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Authors and Affiliations

  1. Lomonosov Institute of Fine Chemical Technologies, Moscow Technological University, Moscow, Russia

    E. A. Katsman, V. Ya. Danyushevsky, P. S. Kuznetsov, V. M. Karpov & V. R. Flid

  2. Hajjah University, Hajjah, Republic of Yemen

    H. A. Al-Wadhaf

Authors
  1. E. A. Katsman
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  2. V. Ya. Danyushevsky
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  3. P. S. Kuznetsov
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  4. V. M. Karpov
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  5. H. A. Al-Wadhaf
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  6. V. R. Flid
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Corresponding author

Correspondence to E. A. Katsman.

Additional information

Original Russian Text © E.A. Katsman, V.Ya. Danyushevsky, P.S. Kuznetsov, V.M. Karpov, H.A. Al-Wadhaf, V.R. Flid, 2017, published in Neftekhimiya, 2017, Vol. 57, No. 6, pp. 813–816.

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Katsman, E.A., Danyushevsky, V.Y., Kuznetsov, P.S. et al. Features of the Kinetics and Mechanism of Stearic Acid Decarbonylation in the Presence of a Silica Gel-Supported Nickel Sulfide Catalyst. Pet. Chem. 57, 1190–1193 (2017). https://doi.org/10.1134/S0965544117060172

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  • DOI: https://doi.org/10.1134/S0965544117060172

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