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Catalytic hydroxycarbonylation of isobutylene with carbon monoxide and polyhydric alcohols in the presence of the Pd(acac)2-PPh3-TsOH system

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Abstract

The reaction of isobutylene hydroalcoxycarbonylation with CO and polyhydric alcohols (ethylene glycol, glycerol) in the presence of the catalytic system Pd(aacac)2-PPh3-TsOH has been investigated. It was found that carbonylation of isobutylene with CO in the presence of ethylene glycol yields a mixture of mono-and diglycol esters of isovaleric acid, irrespective of the initial reactant ratio. During the hydroalcoxycarbonylation of isobutylene with glycerol, either mono- and di- or mono-, di-, and triglycerides of isovaleric acid are formed depending on the reactant ratio.

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References

  1. M. D. Mashkovskii, Medicines 10th Ed. (Meditsina, Moscow, 1987) [in Russian].

    Google Scholar 

  2. E. G. Chepaikin, A. P. Bezruchenko, Kh. A. Suerbaev, and K. M. Shalmagambetov, Neftekhimiya 46, 134 (2006) [Pet. Chem. 46, 117 (2006)].

    CAS  Google Scholar 

  3. V. A. Aver’yanov, N. M. Nosova, and S. A. Batashev, Neftekhimiya 46, 116 (2006) [Pet. Chem. 46, 99 (2006)].

    CAS  Google Scholar 

  4. A. F. Artamonov, Doctoral Dissertation in Chemistry (Kazakh National Univ. Almaty, 2005).

  5. E. G. Chepaikin, A. P. Bezruchenko, A. Ben’ei, and F. Io, Izv. Akad. Nauk SSSR, Ser. Khim., No. 3, 743 (1989).

  6. H. Isa, T. Inagaki, Y. Kiyonaga, and M. Nagayama, BD Patent 2 404 955 (1974); Chem. Abstr. 83 27605 (1975).

  7. H. Isa, T. Inamoto, Y. Kiyonaga, and M. Nagayama, JP Appl. 74 108 013 (1974); Chem. Abstr. 82 155386 (1975).

  8. H. Isa, T. Inagaki, Y. Shimizu, and M. Nagayama, JP Appl. 7 562 925 (1975); Chem. Abstr. 83 96 454 (1975).

  9. N. A. Artamonova, M. I. Goryaev, Yu. A. Morozova, and O. I. Efremova, Izv. Akad. Nauk Kaz. SSR, Ser. Khim., No. 2, 35 (1979).

  10. N. A. Artamonova, A. F. Artamonov, L. P. Petelina, et al., Vestn. Karakalpak. Filiala Akad. Nauk Uz. SSR, No. 3, 13 (1988).

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Authors and Affiliations

  1. Al-Farabi Kazakh National University, ul. al-Farabi 71, Almaty, 050038, Republic of Kazakhstan

    H. A. Suerbaev, B. Zh. Dzhiembaev, I. O. Appazov & G. M. Abyzbekova

  2. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, 142432, Russia

    E. G. Chepajkin

Authors
  1. H. A. Suerbaev
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  2. E. G. Chepajkin
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  3. B. Zh. Dzhiembaev
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  4. I. O. Appazov
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  5. G. M. Abyzbekova
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Correspondence to E. G. Chepajkin.

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Original Russian Text © H.A. Suerbaev, E.G. Chepajkin, B.Zh. Dzhiembaev, I.O. Appazov, G.M. Abyzbekova, 2007, published in Neftekhimiya, 2007, Vol. 47, No. 5, pp. 376–378.

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Suerbaev, H.A., Chepajkin, E.G., Dzhiembaev, B.Z. et al. Catalytic hydroxycarbonylation of isobutylene with carbon monoxide and polyhydric alcohols in the presence of the Pd(acac)2-PPh3-TsOH system. Pet. Chem. 47, 345–347 (2007). https://doi.org/10.1134/S0965544107050064

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  • DOI: https://doi.org/10.1134/S0965544107050064

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