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Formation of an Electrode Deposit under Galvanostatic Conditions

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Abstract

The laws of formation of a continuous deposit layer at a given direct current are considered. Equations are analyzed to calculate the time dependences of overpotential for instantaneous nucleation with kinetic or diffusion control of new-phase growth. The calculated dependences are compared with the experimental ones obtained for silicon electrodeposition from a fluoride–chloride melt.

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ACKNOWLEDGMENTS

This work was supported by the Russian Science Foundation, project no. 16-13-00061.

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Correspondence to V. A. Isaev.

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Translated by K. Shakhlevich

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Isaev, V.A., Grishenkova, O.V., Laptev, M.V. et al. Formation of an Electrode Deposit under Galvanostatic Conditions. Russ. Metall. 2018, 763–766 (2018). https://doi.org/10.1134/S0036029518080086

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  • DOI: https://doi.org/10.1134/S0036029518080086

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