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CALPHAD Modelling of Ag–Pd–Sn Ternary System

  • CHEMOINFORMATICS AND COMPUTER MODELING
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Abstract

CALPHAD modelling of the Ag–Pd–Sn ternary system has been performed. The disordered phases, the melt and the fcc phase were described using the substitutional solution model. Sublattice models were used to describe intermetallic compounds and the ternary phase. The two-sublattice model (Ag,Pd)4(Ag, Sn) used for the ternary phase made it possible to reproduce the inclination of its homogeneity range. The results of the thermodynamic calculation of the Ag–Pd–Sn system are in good agreement with the experimental data on phase equilibria and enthalpies of formation of the liquid. The agreement with the data on the partial Gibbs energy of tin in the liquid is somewhat worse.

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Funding

The present research work was financially supported by Russian Science Foundation (RSF) grant no. 22-23-00565 (https://rscf.ru/en/project/22-23-00565/).

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Authors and Affiliations

  1. Department of Chemistry, Lomonosov Moscow State University, Moscow, Russia

    A. S. Pavlenko, G. P. Zhmurko, E. G. Kabanova, M. A. Kareva, E. A. Ptashkina & V. N. Kuznetsov

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  1. A. S. Pavlenko
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  2. G. P. Zhmurko
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  3. E. G. Kabanova
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  4. M. A. Kareva
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  5. E. A. Ptashkina
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  6. V. N. Kuznetsov
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Correspondence to E. G. Kabanova or V. N. Kuznetsov.

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Pavlenko, A.S., Zhmurko, G.P., Kabanova, E.G. et al. CALPHAD Modelling of Ag–Pd–Sn Ternary System. Russ. J. Phys. Chem. 97, 2006–2012 (2023). https://doi.org/10.1134/S0036024423090145

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