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Solvothermal Synthesis of Polyoxometalate Modified Metal-Organic Framework for Enhanced Removal of Methylene Blue from Aqueous Solution

  • PHYSICAL CHEMISTRY OF SOLUTIONS
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Abstract

Removal of methylene blue (MB) from wastewater is significant to protect the environment. In this study, the facile preparation of phosphomolybdotungstic acid (H6P2Mo15W3O62)-modified metal-organic framework (MIL-96(Al)) materials for MB removal from wastewater is reported. The H6P2Mo15W3O62@MIL-96(Al) exhibited a significantly higher adsorption performance for MB than the pure MIL-96(Al). Best MB adsorption conditions are reported. The adsorption capacity of H6P2Mo15W3O62@MIL-96(Al) at 323 K was 157.73 mg g–1. The adsorption kinetics and isotherms of MB on the modified MIL-96(Al) adsorbent showed that they were basically in agreement with the pseudo-second-order kinetic model and Langmuir model, respectively. The determined thermodynamic parameters show that the adsorption process is exothermic. After five cycles, the adsorbent can still remove 68.5% of the dye, indicating its rather high recyclability.

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ACKNOWLEDGMENTS

This work was kindly supported by the National Natural Science Foundation of China (21171053), Natural Science Foundation of Hubei Province, China (2014CFA131), and Graduate Student Innovation Research Foundation of Hubei Normal University (20190128).

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Authors and Affiliations

  1. Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, College of Chemistry and Chemical Engineering, Hubei Normal University, 435002, Huangshi, China

    Hao Hu, Yun-Peng He, Yi-Lin Zhang, Shi-Ya Feng, Xiong-Jian Li & Shui-Jin Yang

  2. College of Chemistry and Environmental Engineering, Hanjiang Normal University, 442000, Shiyan, China

    Yun Yang

  3. Institute for Advanced Materials of Hubei Normal University, 435002, Huangshi, China

    Shui-Jin Yang

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  1. Hao Hu
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  2. Yun-Peng He
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  3. Yi-Lin Zhang
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  4. Shi-Ya Feng
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  5. Xiong-Jian Li
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  6. Yun Yang
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Correspondence to Shui-Jin Yang.

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Hu, H., He, YP., Zhang, YL. et al. Solvothermal Synthesis of Polyoxometalate Modified Metal-Organic Framework for Enhanced Removal of Methylene Blue from Aqueous Solution. Russ. J. Phys. Chem. 96 (Suppl 1), S44–S50 (2022). https://doi.org/10.1134/S0036024422140138

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  • DOI: https://doi.org/10.1134/S0036024422140138

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