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Effect of the Nature of a Support on the Activity of Catalysts Based on 1% Cs/Me0.1Co2.9O4 (Me = Ni, Mg) in the Low-Temperature N2O Decomposition

  • IN COMMEMORATION OF ACADEMICIAN V.V. LUNIN: SELECTED CONTRIBUTIONS FROM HIS STUDENTS AND COLLEAGUES
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Abstract

The effect of the support (α-Al2O3, Mg2Al4Si5O18, CeO2, TiO2) on the properties of the catalysts based on Ni, Mg-substituted cobalt spinel is investigated via X-ray diffraction, BET adsorption, and О2 temperature-programmed desorption. Their catalytic activity in the reaction of nitrous oxide decomposition at temperatures of 190–400°C is studied. It is shown that the most active and catalytic poison (O2, H2O)–resistant catalyst is one based on magnesium-substituted cobalt spinel on a corundum support 1% Cs/Mg0.1Co2.9O4/α-Al2O3.

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Funding

This work was performed as part of a State Task for the Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    L. A. Isupova & Yu. A. Ivanova

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  1. L. A. Isupova
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  2. Yu. A. Ivanova
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Correspondence to L. A. Isupova.

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Translated by E. Glushachenkova

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Isupova, L.A., Ivanova, Y.A. Effect of the Nature of a Support on the Activity of Catalysts Based on 1% Cs/Me0.1Co2.9O4 (Me = Ni, Mg) in the Low-Temperature N2O Decomposition. Russ. J. Phys. Chem. 95, 503–511 (2021). https://doi.org/10.1134/S0036024421030134

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