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Proton magnetic relaxation study of the thermodynamic characteristics of water adsorbed by cellulose fibers

  • Physical Chemistry of Surface Phenomena
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Abstract

The possibility of determining the thermodynamic parameters that characterize the sorption properties of cellulose and the state of water associated with its fibers is demonstrated using modern concepts of the structure of this vegetable polymer and methods based on theories of adsorption and NMR relaxation in heterogeneous systems.

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References

  1. S. Brunauer, P. H. Emmett, and E. Teller, J. Am. Chem. Soc. 60, 309 (1938).

    Article  CAS  Google Scholar 

  2. E. A. Guggenheim, Application of Statistical Mechanics (Clarendon, Oxford, 1966), p. 186.

    Google Scholar 

  3. R. B. Anderson, J. Am. Chem. Soc. 68, 686 (1946).

    Article  CAS  Google Scholar 

  4. J. H. de Boer, The Dynamical Character of Adsorption, 2nd ed. (Clarendon, Oxford, 1953), p. 200.

    Google Scholar 

  5. I. Langmuir, J. Am. Chem. Soc. 38, 2221 (1916).

    Article  CAS  Google Scholar 

  6. S. Gregg and K. Sing, Adsorption, Surface Area, and Porosity (Academic, New York, 1982).

    Google Scholar 

  7. M. M. Dubinin, Zh. Fiz. Khim. 61, 1301 (1987).

    CAS  Google Scholar 

  8. Yu. B. Grunin, Doctoral (Chem.) Dissertation (Riga, 1989).

    Google Scholar 

  9. L. Yu. Grunin, Yu. B. Grunin, V. I. Talantsev, et al., Polym. Sci., Ser. A 57, 43 (2015).

    Article  CAS  Google Scholar 

  10. Yu. B. Grunin, L. Yu. Grunin, V. I. Talantcev, et al., Biophysics 60, 43 (2015).

    Article  CAS  Google Scholar 

  11. Y. Nishiyama, P. Langan, and H. Chanzy, J. Am. Chem. Soc. 124 (31), 9074 (2002).

    Article  CAS  Google Scholar 

  12. Y. Nishiyama, J. Sugiyama, H. Chanzy, et al., J. Am. Chem. Soc. 125, 14300 (2003).

    Article  CAS  Google Scholar 

  13. Y. Nishiyama, G. P. Johnson, A. D. French, et al., Biomacromol. 9, 3133 (2008).

    Article  CAS  Google Scholar 

  14. R. M. Brown, J. Polym. Sci., Ser. A: Polym. Chem. 42, 487 (2004).

    Article  CAS  Google Scholar 

  15. Y. B. Grunin, L. Y. Grunin, E. A. Nikolskaya, et al., Polym. Sci., Ser. A 54, 201 (2012).

    Article  CAS  Google Scholar 

  16. V. P. Nikolaev, A. A. Ageev, and Yu. G. Frolov, Tr. Mosk. Khim.-Tekhn. Inst. Mendeleeva, No. 101, 84 (1978).

    Google Scholar 

  17. www.nmr-design.com.

  18. Ya. I. Frenkel’, Kinetic Theory of Liquids (Nauka, Moscow, 1975) [in Russian].

    Google Scholar 

  19. V. I. Chizhik, Nuclear Magnetic Relaxation (St. Petersburg, 2004) [in Russian].

    Google Scholar 

  20. A. Abragam, The Principles of Nuclear Magnetism (Oxford Univ., Oxford, 1961).

    Google Scholar 

  21. Yu. B. Grunin, L. Yu. Grunin, and E. A. Nikol’skaya, Russ. J. Phys. Chem. A 81, 1165 (2007).

    Article  CAS  Google Scholar 

  22. Ya. I. Gerasimov, Course of Physical Chemistry (Khimiya, Moscow, 1973), Vols. 1, 2 [in Russian].

    Google Scholar 

  23. Yu. B. Grunin, L. Yu. Grunin, E. A. Nikolskaya, et al., Russ. J. Phys. Chem. A 87, 100 (2013).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Volga State University of Technology, Yoshkar-Ola, 424000, Mari El, Russia

    Yu. B. Grunin, L. Yu. Grunin, D. S. Masas, V. I. Talantsev & N. N. Sheveleva

  2. Mari State University, Yoshkar-Ola, 424001, Mari El, Russia

    L. Yu. Grunin

Authors
  1. Yu. B. Grunin
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  2. L. Yu. Grunin
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  3. D. S. Masas
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  4. V. I. Talantsev
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  5. N. N. Sheveleva
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Corresponding author

Correspondence to L. Yu. Grunin.

Additional information

Original Russian Text © Yu.B. Grunin, L.Yu. Grunin, D.S. Masas, V.I. Talantsev, N.N. Sheveleva, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 11, pp. 1696–1700.

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Grunin, Y.B., Grunin, L.Y., Masas, D.S. et al. Proton magnetic relaxation study of the thermodynamic characteristics of water adsorbed by cellulose fibers. Russ. J. Phys. Chem. 90, 2249–2253 (2016). https://doi.org/10.1134/S003602441611008X

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  • DOI: https://doi.org/10.1134/S003602441611008X

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