Abstract
The effects of the nature and composition of solvents on the thermodynamic characteristics of the adsorption states of hydrogen on nickel were studied. The adsorption can be described in terms of the thermodynamic model of a surface with a discrete nonhomogeneity for three individual forms of adsorbed hydrogen. The thermodynamic characteristics of the individual forms of hydrogen adsorbed on porous nickel from aqueous solutions of sodium hydroxide, dimethylformamide, methanol, and ethanol were determined.
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References
G. K. Boreskov, Heterogeneous Catalysis (Nauka, Moscow, 1986; Nova Sci., New York, 2003).
L. V. Babenkova and I. N. Blagoveshchenskaya, Zh. Fiz. Khim. 58, 947 (1984).
D. V. Sokol’skii and A. M. Sokol’skaya, Metals as Hydrogenation Catalysts (Nauka, Alma-Ata, 1970), pp. 45, 143 [in Russian].
E. F. Yakubenok, I. I. Yukel’son, and Yu. A. Podvyazkin, in Catalytic Reactions in Liquid Phase (Nauka, Alma-Ata, 1972), Vol. 2, p. 116 [in Russian].
L. V. Babenkova, N. M. Popova, I. N. Blagoveshchenskaya, and L. V. Tyuleneva, Tr. Inst. Org. Katal. Elektrokhim. AN KazSSR 10, 71 (1975).
N. M. Popova, L. V. Babenkova, and G. A. Savel’eva, Adsorption and Interaction of the Simplest Gases with Group VIII Metals (Nauka, Alma-Ata, 1979), pp. 9, 261 [in Russian].
M. V. Ulitin, A. V. Barbov, O. V. Lefedova, and V. P. Gostikin, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 48(7), 62 (2005).
D. V. Filippov, M. V. Ulitin, V. V. Chernikov, and A. V. Barbov, Zh. Fiz. Khim. 79, 880 (2005) [Russ. J. Phys. Chem. A 79, 758 (2005)].
M. V. Lukin, A. V. Barbov, and M. V. Ulitin, Zh. Fiz. Khim. 74, 1089 (2000) [Russ. J. Phys. Chem. A 74, 970 (2000)].
M. V. Ulitin, A. V. Barbov, Yu. D. Pankrat’ev, and S. A. Loginov, Zh. Fiz. Khim. 71, 329 (1997) [Russ. J. Phys. Chem. A 71, 270 (1997)].
M. V. Ulitin and V. P. Gostikin, Zh. Fiz. Khim. 59, 2266 (1985).
M. V. Ulitin, A. V. Barbov, V. G. Shalyukhin, and V. P. Gostikin, Zh. Prikl. Khim. 66, 497 (1993).
A. L. Klyachko, Kinet. Katal. 91, 1218 (1978).
A. M. Tolmachev, Zh. Fiz. Khim. 56, 2022 (1982).
L. V. Babenkova and I. N. Naidina, Usp. Khim. AN SSSR 63, 578 (1994).
M. V. Shepelev, A. V. Barbov, M. V. Ulitin, and S. V. Denisov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 50(8), 25 (2007).
A. V. Barbov, M. V. Ulitin, Yu. D. Pankrat’ev, and N. G. Koroleva, Zh. Fiz. Khim. 69, 915 (1995).
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Original Russian Text © A.V. Barbov, M.V. Shepelev, D.V. Filippov, M.V. Ulitin, 2010, published in Zhurnal Fizicheskoi Khimii, 2010, Vol. 84, No. 9, pp. 1757–1763.
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Barbov, A.V., Shepelev, M.V., Filippov, D.V. et al. Effects of the nature and composition of the solvent on the thermodynamic characteristics of the individual forms of hydrogen adsorbed on the surface of porous nickel. Russ. J. Phys. Chem. 84, 1605–1610 (2010). https://doi.org/10.1134/S0036024410090281
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DOI: https://doi.org/10.1134/S0036024410090281