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Cobalt tetrasulfophthalocyaninate as a catalyst of the reduction of nitrite with thiourea dioxide

  • Chemical Kinetics and Catalysis
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Abstract

The kinetics of reduction of nitrite with thiourea dioxide in the presence of cobalt tetrasulfophth-alocyaninate was studied. The process was shown to involve the CoII ↔ CoI catalytic cycle. The kinetic parameters of the reduction of CoII and CoI tetrasulfophthalocyaninates were determined

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Correspondence to S. V. Makarov.

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Original Russian Text © A.S. Pogorelova, S.V. Makarov, E.S. Ageeva, R. Silagi-Dumitresku, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 12, pp. 2250–2254.

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Pogorelova, A.S., Makarov, S.V., Ageeva, E.S. et al. Cobalt tetrasulfophthalocyaninate as a catalyst of the reduction of nitrite with thiourea dioxide. Russ. J. Phys. Chem. 83, 2050–2053 (2009). https://doi.org/10.1134/S0036024409120085

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  • DOI: https://doi.org/10.1134/S0036024409120085

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