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Synthesis and Study of Si–Ti Mixed Oxides Modified with Dibenzo-18-Crown-6 Complexes with Metal Cations

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Composites based on SiO2–TiO2 and dibenzo-18-crown-6 (DBC) complexes with rare earth element (REE), sodium, cesium, barium, and strontium cations, including ion-imprinted composites, were prepared by sol–gel process. According to thermogravimetric analysis data, the greater part of water and dimethylformamide in the composites with DBC complexes were bound into a complex with the crown ether and the metal cation, which decomposed at 210–230°C. The possibility of fabricating efficient and selective sorbents for REEs by imprinting REE cations or cheap Na(I) cation, which has a similar size, into the DBC/SiO2–TiO2 composite was demonstrated; such sorbents could be used in practice.

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Funding

This study was performed within the framework of the state assignments AAAA-A19-119012290117-6 and AAAA-A19-119012490007-8 using equipment of the center for collective use “Spectroscopy and Analysis of Organic Compounds ” (CCU “SAOC”).

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Authors and Affiliations

  1. Postovsky Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, 620108, Yekaterinburg, Russia

    O. V. Fedorova, E. S. Filatova, O. V. Koryakova, M. S. Valova, A. I. Maksimovskikh & G. L. Rusinov

  2. Belarusian State Technological University, 220006, Minsk, Belarus

    A. N. Murashkevich & A. O. Kravchenko

  3. Ural Federal University named after the first President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia

    G. L. Rusinov

Authors
  1. O. V. Fedorova
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  2. A. N. Murashkevich
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  3. E. S. Filatova
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  4. O. V. Koryakova
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  5. M. S. Valova
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  6. A. O. Kravchenko
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  7. A. I. Maksimovskikh
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  8. G. L. Rusinov
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Corresponding author

Correspondence to O. V. Fedorova.

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Translated by Z. Svitanko

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Fedorova, O.V., Murashkevich, A.N., Filatova, E.S. et al. Synthesis and Study of Si–Ti Mixed Oxides Modified with Dibenzo-18-Crown-6 Complexes with Metal Cations. Russ. J. Inorg. Chem. 67, 1527–1536 (2022). https://doi.org/10.1134/S0036023622100345

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