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Synthesis and Spectroscopy of Substituted Benzoylacetonates of Boron Difluoride

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Abstract

A simple method is proposed for the preparative synthesis of substituted benzoylacetonates of boron difluoride in one step from donor-substituted arenes by acetoacetylation under the action of boron trifluoride. The effect of the nature of alkyl and aryl substituents on the phenyl ring of boron difluoride benzoylacetonates on their spectral and luminescent properties is analyzed. It is shown that alkyl substituents insignificantly increase the luminescence quantum yield. A significant increase in the luminescence quantum yield up to 0.75 and a significant bathochromic shift up to 536 nm are achieved with an increase in the π-system of the molecule: the transition from phenyl to naphthyl, diphenyl, and anthracyl.

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation, State Assignment no. 0205-2021-0001.

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    A. G. Mirochnik, Z. N. Puzyrkov & E. V. Fedorenko

  2. Far Eastern Federal University, 690922, Vladivostok, Russia

    Z. N. Puzyrkov & I. V. Svistunova

Authors
  1. A. G. Mirochnik
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  2. Z. N. Puzyrkov
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  3. E. V. Fedorenko
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  4. I. V. Svistunova
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Correspondence to E. V. Fedorenko.

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Translated by V. Avdeeva

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Mirochnik, A.G., Puzyrkov, Z.N., Fedorenko, E.V. et al. Synthesis and Spectroscopy of Substituted Benzoylacetonates of Boron Difluoride. Russ. J. Inorg. Chem. 67, 1425–1432 (2022). https://doi.org/10.1134/S003602362209008X

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  • DOI: https://doi.org/10.1134/S003602362209008X

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