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Ceramics in the K2O–CaO–SO3–P2O5 System

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Ceramics in the K2O–CaO–SO3–P2O5 system has been prepared from powder mixtures of potassium hydrogen sulfate KHSO4 and calcium hydroxyapatite Ca10(PO4)6(OH)2 at molar ratios KHSO4/Ca10(PO4)6(OH)2 = 2/1, 4/1, and 6/1. The powder mixtures were obtained in acetone under mechanical activation conditions using a planetary mill. After homogenization, the phase composition of powder mixtures included monetite CaHPO4, singenite K2Ca(SO4)2⋅H2O, and calcium hydroxyapatite Сa10(PO4)6(OH)2. After firing at 700–900°C the phase composition of ceramics manufactured from the powder mixtures included phases of potassium-substituted tricalcium phosphate Сa10K(PO4)7 and calciolangbeinite K2Ca2(SO4)3, as well as potassium sulfate K2SO4 at molar ratios KHSO4/Ca10(PO4)6(OH)2 = 4/1 and 6/1. Ceramic materials whose phase composition includes calciolangbeinite K2Ca2(SO4)3 and potassium-substituted tricalcium phosphate Сa10K(PO4)7 can be used as resorbable porous material for curing defects of bone tissue by regenerative medicine methods or as a matrix on designing luminescent/thermoluminescent materials. Ceramic materials in K2O–CaO–SO3–P2O5 system have been obtained for the first time, therefore, additional studies are necessary to determine the optimal phase ratio for the noted applications.

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ACKNOWLEDGMENTS

This work was performed using equipment purchased due to financial support from the Development Program of the Moscow State University.

Funding

This work was financially supported by the Russian Foundation for Basic Research (project no. 20-03-00550).

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Authors and Affiliations

  1. Moscow State University, 119991, Moscow, Russia

    T. V. Safronova, T. B. Shatalova, S. A. Tikhonova & G. K. Kazakova

  2. Kosygin State University (Technology, Design, Art), 117997, Moscow, Russia

    M. M. Akhmedov

Authors
  1. T. V. Safronova
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  2. M. M. Akhmedov
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  3. T. B. Shatalova
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  4. S. A. Tikhonova
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  5. G. K. Kazakova
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Contributions

T.V. Safronova formulated the aim of work, planned experiment, and wrote the text of the paper; M.M. Akhmedov suggested idea, prepared samples, and treated XRD data; T.B. Shatalova performed thermal analysis and interpreted its data; S.A. Tikhonova and G.K. Kazakova performed electron-microscopic study of prepared powders and ceramic samples. All the authors participated in results discussion.

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Correspondence to T. V. Safronova.

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The authors declare that they have no conflicts of interest.

ADDITIONAL INFORMATION

This paper was published further to the Sixth Interdisciplinary Scientific Forum with the International Participation “Novel Materials and Promising Technology,” Moscow, November 23–26, 2020. https://n-materials.ru.

Additional information

Translated by I. Kudryavtsev

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Safronova, T.V., Akhmedov, M.M., Shatalova, T.B. et al. Ceramics in the K2O–CaO–SO3–P2O5 System. Russ. J. Inorg. Chem. 66, 1057–1066 (2021). https://doi.org/10.1134/S0036023621080246

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