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Tris(2-metoxy-5-chlorophenyl)antimony Dicarboxylates (5-Cl-2-MeO-C6H3)3Sb[OC(O)R]2, Where R = CH2Br, CH2C6H4F-3, and C6H3F2-2,3: Synthesis and Structure

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Abstract

In a crystal of tris(2-methoxy-5-chlorophenyl)antimony benzene solvate (5-Cl-2-MeO-C6H3)3Sb (I) ⋅ 1/2С6Н6 synthesized from SbCl3 and 2-methoxy-5-chlorophenyllithium with recrystallization from benzene, the antimony atoms are in a trigonal environment of ligands with the oxygen atoms of MeO groups coordinated to the metal atom (intramolecular Sb∙∙∙OМе distances are 3.053(1), 3.054(1), and 3.011(1) Å, CN = 3 + 3). The effect of tert-butyl hydroperoxide on a mixture of tris(2-methoxy-5-chlorophenyl)antimony and bromoacetic, 3-fluorophenylacetic, and 2,3-difluorobenzoic acids in ether leads to the formation of trigonal bipyramidal triarylantimony dicarboxylates (5-Cl-2-MeO-C6H3)3Sb[OC(O)R]2, where R = CH2Br (II), CH2C6H4F-3 (III), C6H3F2-2,3 (IV) with carboxylate ligands in apical positions. In crystals of compounds II–IV, the metal atom is additionally coordinated to the oxygen atoms of О=С and МеО groups.

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REFERENCES

  1. Cambridge Crystallographic Data Center (2019). http://www.ccdc.cam.ac.uk.

  2. K. Onishi, M. Douke, T. Nakamura, et al., J. Inorg. Biochem. 117, 77 (2012). https://doi.org/10.1016/j.jinorgbio.2012.09.009

    Article  CAS  PubMed  Google Scholar 

  3. D. Copolovici, F. Isaia, H. J. Breunig, et al., RSC Advances 4, 26569 (2014). https://doi.org/10.1039/C4RA03482A

    Article  Google Scholar 

  4. D. Copolovici, V. R. Bojan, C. I. Rat, et al., Dalton Trans. 39, 6410 (2010). https://doi.org/10.1039/C003318A

    Article  CAS  PubMed  Google Scholar 

  5. S. Okajima, S. Yasuike, N. Kakusawa, et al., J. Organomet. Chem. 656, 234 (2002). https://doi.org/10.1016/S0022-328X(02)01622-4

    Article  CAS  Google Scholar 

  6. H. Yamamichi, S. Matsukawa, S. Kojima, et al., Heteroat. Chem. 22, 553 (2011). https://doi.org/10.1002/hc.20721

    Article  CAS  Google Scholar 

  7. T. Reznicek, L. Dostal, A. Ruzicka, et al., Appl. Organomet. Chem. 26, 237 (2012). https://doi.org/10.1002/aoc.2845

    Article  CAS  Google Scholar 

  8. T. Obata, M. Matsumura, M. Kawahata, et al., J. Organomet. Chem. 807, 17 (2016). https://doi.org/10.1016/j.jorganchem.2016.02.008

    Article  CAS  Google Scholar 

  9. Y. Matano, H. Nomura, T. Hisanaga, et al., Organometallics 23, 5471 (2004). https://doi.org/10.1021/om0494115

    Article  CAS  Google Scholar 

  10. V. V. Sharutin and O. K. Sharutina, Russ. J. Inorg. Chem. 60, 1491 (2015). https://doi.org/10.1134/S0036023615120219

    Article  CAS  Google Scholar 

  11. V. V. Sharutin, V. S. Senchurin, O. K. Sharutina, et al., Russ. Coord. Chem. 37, 781 (2011). https://doi.org/10.1134/S1070328411090089

    Article  CAS  Google Scholar 

  12. V. V. Sharutin, V. S. Senchurin, O. K. Sharutina, et al., Russ. J. Gen. Chem. 81, 2102 (2011). https://doi.org/10.1134/S1070363211100100

    Article  CAS  Google Scholar 

  13. V. V. Sharutin, V. S. Senchurin, O. K. Sharutina, et al., Russ. J. Inorg. Chem. 56, 1561 (2011). https://doi.org/10.1134/S0036023611100196

    Article  CAS  Google Scholar 

  14. Y. Matano, H. Nomura, and H. Suzuki, Inorg. Chem. 39, 1340 (2000). https://doi.org/10.1021/ic991120e

    Article  CAS  Google Scholar 

  15. Y. Matano, H. Nomura, and H. Suzuki, Inorg. Chem. 41, 1940 (2002). https://doi.org/10.1021/ic0110575

    Article  CAS  PubMed  Google Scholar 

  16. V. V. Sharutin, O. K. Sharutina, V. S. Senchurin, et al., Russ. J. Gen. Chem. 82, 1665 (2012). https://doi.org/10.1134/S1070363212100064

    Article  CAS  Google Scholar 

  17. V. V. Sharutin, O. K. Sharutina, and V. S. Senchurin, Russ. J. Inorg. Chem. 59, 326 (2014). https://doi.org/10.1134/S0036023614040202

    Article  CAS  Google Scholar 

  18. T. Iftikhar, M. K. Rauf, S. Sarwar, et al., J. Organomet. Chem. 851, 89 (2017). https://doi.org/10.1016/j.jorganchem.2017.09.002

    Article  CAS  Google Scholar 

  19. R. Mushtaq, M. K. Rauf, M. Bond, et al., Appl. Organomet. Chem. 30, 465 (2016). https://doi.org/10.1002/aoc.3456

    Article  CAS  Google Scholar 

  20. R. Mushtaq, M. K. Rauf, M. Bolte, et al., Appl. Organomet. Chem. 31, e3606 (2017). https://doi.org/10.1002/aoc.3606

    Article  Google Scholar 

  21. M. I. Ali, M. K. Rauf, A. Badshah, et al., J. Chem. Soc., Dalton Trans. 42, 16733 (2013). https://doi.org/10.1039/c3dt51382c

    Article  CAS  Google Scholar 

  22. Y. Q. Ma, L. Yu, and J. S. Li, Heteroat. Chem. 13, 299 (2002). https://doi.org/10.1002/hc.10033

    Article  CAS  Google Scholar 

  23. A. Islam, SilvaJ. G. Da, F. M. Berbet, et al., Molecules 19, 6009 (2014). https://doi.org/10.3390/molecules19056009

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  24. R. C. Liu, Y. Q. Ma, L. Yu, et al., Appl. Organomet. Chem. 17, 662 (2003). https://doi.org/10.1002/aoc.491

    Article  CAS  Google Scholar 

  25. J. S. Li, R. C. Liu, X. B. Chi, et al., Inorg. Chim. Acta 357, 2176 (2004). https://doi.org/10.1016/j.ica.2003.12.012

    Article  CAS  Google Scholar 

  26. Y. Ma, J. Li, Z. Xuan, et al., J. Organomet. Chem. 620, 235 (2001). https://doi.org/10.1016/S0022-328X(00)00799-3

    Article  CAS  Google Scholar 

  27. J. S. Li, Y. Q. Ma, J. R. Cui, et al., Appl. Organomet. Chem. 15, 639 (2001). https://doi.org/10.1002/aoc.200

    Article  CAS  Google Scholar 

  28. X.-Y. Zhang, L. Cui, X. Zhang, et al., J. Mol. Struct. 1134, 742 (2017). https://doi.org/10.1016/j.molstruc.2017.01.039

    Article  CAS  Google Scholar 

  29. K. Lowe and R. Powell, J. Fluorine Chem. 109, 1 (2001). https://doi.org/10.1016/S0022-1139(01)00371-2

    Article  CAS  Google Scholar 

  30. B. E. Smart, J. Fluorine Chem. 109, 3 (2001). https://doi.org/10.1016/S0022-1139(01)00375-X

    Article  CAS  Google Scholar 

  31. O. K. Sharutin and A. N. Sharutina, Efremov, and P. A. Slepukhin, Russ. J. Inorg. Chem. 65, 992. https://doi.org/10.1134/S0036023620070190

  32. B. K. Park and N. R. Kitteringham, Drug Metab. Rev. 26, 605 (1994). https://doi.org/10.3109/03602539408998319

    Article  CAS  Google Scholar 

  33. P. Maienfisch and R. G. Hall, Chimia Int. J. Chem. 58, 93 (2004). https://doi.org/10.2533/000942904777678091

    Article  CAS  Google Scholar 

  34. SMART and SAINT-Plus. Versions 5.0. Data Collection and Processing Software for the SMART System (Bruker, 1998).

    Google Scholar 

  35. SHELXTL/PC. Versions 5.10. An Integrated System for Solving, Refining and Displaying Crystal Structures from Diffraction Data (Bruker, 1998).

    Google Scholar 

  36. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009). https://doi.org/10.1107/S0021889808042726

    Article  CAS  Google Scholar 

  37. E. A. Adams, J. W. Kolis, and W. T. Pennington, Acta Crystallogr., Sect. C 46, 917 (1990). https://doi.org/10.1071/C96042

    Article  Google Scholar 

  38. A. N. Sobolev, I. P. Romm, V. K. Belskii, et al., J. Organomet. Chem. 179, 153 (1979). https://doi.org/10.1016/S0022-328X(00)95217-3

    Article  CAS  Google Scholar 

  39. B. Cordero, V. Gomez, A. E. Platero-Prats, et al., Dalton Trans. 21, 2832 (2008). https://doi.org/10.1039/B801115J

    Article  Google Scholar 

  40. M. Mantina, A. C. Chamberlin, R. Valero, et al., J. Phys. Chem. A 113, 5806 (2009). https://doi.org/10.1021/jp8111556

    Article  CAS  Google Scholar 

  41. V. V. Sharutin, O. K. Sharutina, V. S. Senchurin, et al., Russ. J. Gen. Chem. 79, 2131 (2009). https://doi.org/10.1134/S1070363209100107

    Article  CAS  Google Scholar 

  42. E. V. Artem’eva, V. V. Sharutin, O. K. Sharutina, et al., Russ. J. Inorg. Chem. 65, 22 (2020). https://doi.org/10.1134/S0036023620010039

    Article  Google Scholar 

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  1. National South Ural State Research University, 454080, Chelyabinsk, Russia

    V. V. Sharutin & O. K. Sharutina

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Sharutin, V.V., Sharutina, O.K. Tris(2-metoxy-5-chlorophenyl)antimony Dicarboxylates (5-Cl-2-MeO-C6H3)3Sb[OC(O)R]2, Where R = CH2Br, CH2C6H4F-3, and C6H3F2-2,3: Synthesis and Structure. Russ. J. Inorg. Chem. 66, 361–366 (2021). https://doi.org/10.1134/S0036023621030153

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