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Аl2(SO4)3 ⋅ 8(CH3)2SO ⋅ 3Н2О Glass as a Precursor for the Synthesis of Crystalline Аl2(SO4)3 ⋅ 8(CH3)2SO

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Abstract

The new compound Аl2(SO4)3 ⋅ 8(CH3)2SO, which cannot be prepared by direct synthesis, has been synthesized from an Аl2(SO4)3 ⋅ 8(CH3)2SO ⋅ 3Н2О glass. The compound has been identified by X-ray diffraction. Based on IR spectra, it has been concluded that the Al3+ ion has mixed coordination to dimethylsulfoxide (DMSO) molecules, and the ligands are linked to each other through the S and O atoms.

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ACKNOWLEDGMENTS

This study was performed on the equipment of the Shared Facilities Center of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    I. A. Kirilenko, G. P. Panasyuk, L. A. Azarova, I. V. Kozerozhets & M. G. Vasil’ev

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 199991, Moscow, Russia

    L. I. Demina

Authors
  1. I. A. Kirilenko
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  2. G. P. Panasyuk
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  3. L. A. Azarova
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  4. L. I. Demina
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  5. I. V. Kozerozhets
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  6. M. G. Vasil’ev
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Correspondence to I. A. Kirilenko.

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Translated by E. Glushachenkova

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Kirilenko, I.A., Panasyuk, G.P., Azarova, L.A. et al. Аl2(SO4)3 ⋅ 8(CH3)2SO ⋅ 3Н2О Glass as a Precursor for the Synthesis of Crystalline Аl2(SO4)3 ⋅ 8(CH3)2SO. Russ. J. Inorg. Chem. 64, 941–945 (2019). https://doi.org/10.1134/S0036023619070106

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  • DOI: https://doi.org/10.1134/S0036023619070106

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