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Palladium Complexes [Ph3PC6H11-cyclo]+[PdBr3(Dmso-S)]–, [Ph3PBu]+[PdCl3(Dmso-S)]–, and [Ph3PCH2CH=CHCH2PPh3]2+[PdCl4]2–. Dmf: Synthesis and Structure

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Ph3PC6H11-cyclo)]+[PdBr3(Dmso)]– (I) and [Ph3PBu]+[PdCl3(Dmso)]– (II) have been synthesized by the reactions of tetrahydrobromopalladic acid with (cyclohexyl)triphenylphosphonium bromide and tetrahydrochloropalladic acid with butyltriphenylphosphonium chloride in water with further recrystallization from dimethyl sulfoxide. [Ph3PCH2CH=CHCH2PPh3]2+[PdCl4]2–. Dmf (III) has been synthesized by a similar reaction of tetrahydrochloropalladic acid with butylene-2-bis(triphenylphosphonium) dichloride with recrystallization from N,N-dimethylformamide. According to X-ray diffraction data, P–C bond lengths and CPC angles in cations of complexes I–III variate within 1.778(2)–1.811(4) Å and 106.1(2)°–112.0(2)°, respectively. Dimethyl sulfoxide molecules in anions of complexes I and II are S-coordinated, and Pd–S bonds are 2.2478(14) and 2.2466(6) Å, while Pd–Cl distances in centrosymmetric square anions of complex III are 2.3143(5) and 2.3170(5) Å, and ClPdCl trans angles are 180°. The structural organization of crystals is formed by weak hydrogen bonds C–H...Br, C–H...Cl, and C–H...O.

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Authors and Affiliations

  1. South Ural State University (National Research University), Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina & V. S. Senchurin

  2. Lobachevskii National Research State University, Nizhny Novgorod, 603950, Russia

    P. V. Andreev

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. V. S. Senchurin
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  4. P. V. Andreev
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, V.S. Senchurin, P.V. Andreev, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 6, pp. 712–717.

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Sharutin, V.V., Sharutina, O.K., Senchurin, V.S. et al. Palladium Complexes [Ph3PC6H11-cyclo]+[PdBr3(Dmso-S)]–, [Ph3PBu]+[PdCl3(Dmso-S)]–, and [Ph3PCH2CH=CHCH2PPh3]2+[PdCl4]2–. Dmf: Synthesis and Structure. Russ. J. Inorg. Chem. 63, 747–752 (2018). https://doi.org/10.1134/S0036023618060220

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  • DOI: https://doi.org/10.1134/S0036023618060220

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