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Synthesis and structure of tetraphenylantimony and triphenylantimony 4-oxybenzoates

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Abstract

Solvate Ph3Sb[OC(O)C6H4(OH-4)]2 · 1/2Et2O (I) has been synthesized by the reaction between triphenylantimony and 4-oxybenzoic acid in the presence of hydrogen peroxide in diethyl ether. Tetraphenylantimony 4-oxybenzoate, which crystallizes from DMSO in the form of solvate Ph4SbOC(O)C6H4(OH-4) · DMSO (II), has been synthesized from pentaphenylantimony and triphenylantimony bis(4-oxybenzoate) or 4-oxybenzoic acid. According to X-ray diffraction data, an antimony atom in molecules of compounds I and II has a trigonal bipyramidal coordination. Crystals of compound I contain two crystallographically independent types of molecules (A and B). The Sb-C and Sb-O distances, the equatorial CSbC and axial OSbO angles are, respectively, 2.083(9)–2.103(8)Å; 2.068(5), 2.128(5)Å; 117.6(3)°–124.2(3)° and 171.5(2)° (IA); 2.103(9)–2.135(8)Å; 2.086(5), 2.154(6)Å;110.2(3)°–138.0(4)° and 174.8(2)° (IB). In compound II, Sb-C is 2.117(2)–2.175(2) Å, Sb-O is 2.247(2) Å, and CeqSbCeq and OSbCax angles are 110.89(9)°–133.30(9)° and 177.05(7)°, respectively. The Sb…O=C intramolecular contacts are 3.151(7), 3.153(8) Å (IA), 2.985(8), 3.008(9) Å (IB), and 2.975(5) Å (II). Molecules IA and IB are conformation isomers, which differ from each other by the arrangement of carboxyl groups with respect to the equatorial plane.

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Authors and Affiliations

  1. National South Ural State Research University, pr. Lenina 76, Chelyabinsk, 454080, Russia

    V. V. Sharutin, O. K. Sharutina & S. V. Senchurin

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. S. V. Senchurin
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Correspondence to V. V. Sharutin.

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Original Russian Text © V.V. Sharutin, O.K. Sharutina, S.V. Senchurin, 2014, published in Zhurnal Neorganicheskoi Khimii, 2014, Vol. 59, No. 9, pp. 1182–1186.

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Sharutin, V.V., Sharutina, O.K. & Senchurin, S.V. Synthesis and structure of tetraphenylantimony and triphenylantimony 4-oxybenzoates. Russ. J. Inorg. Chem. 59, 951–955 (2014). https://doi.org/10.1134/S0036023614090174

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