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Polythermal section Sn4P3-Sn4As3

  • Physicochemical analysis of inorganic systems
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Abstract

The T-x diagram of the polythermal section Sn4P3-Sn4As3 of the Sn-P-As system was constructed using the results of X-ray powder diffraction and differential thermal analyses. A continuous series of solid solutions (Sn4P3) x (Sn4As3)1 − x was found to exist. The section is not quasi-binary; in a Sn4As3-rich region, this section intersects the peritectic part of the three-phase volume (L + SnAs + α) of the ternary diagram.

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Original Russian Text © G.V. Semenova, E.Yu. Kononova, T.P. Sushkova, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 9, pp. 1242–1245.

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Semenova, G.V., Kononova, E.Y. & Sushkova, T.P. Polythermal section Sn4P3-Sn4As3 . Russ. J. Inorg. Chem. 58, 1112–1114 (2013). https://doi.org/10.1134/S0036023613090192

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  • DOI: https://doi.org/10.1134/S0036023613090192

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