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Synthesis and characterization of Hg(II) and Zn(II) complexes based on 3-[(4-chlorophenylamido)]propenoic acid

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Abstract

3-[(4-Chlorophenylamido)]propenoic acid has been synthesized by reaction of maleic anhydride and 4-chloroaniline in 1:1 molar ratio in glacial acetic acid and its metal complexes have been synthesized by the reaction of 3-[(4-chlorophenylamido)]propenoic acid with HgCl2 and [Zn(CH3COO)2] · 2H2O in 2: 1 molar ratio, respectively. All the synthesized compounds have been characterized by the elemental analysis, IR, UV/Vis and NMR (1H, 13C) spectroscopy. Conductance for the reported compounds has been recorded in ethanol and suggests the non-electro lytic nature of complexes. IR data of metal complexes shows that the ligand is bound to the metal via both carboxylate oxygen atoms and complexes exhibits 4-coordinated geometry in solid state. NMR (1H, 13C) study confirms the structure of the 3-[(4-chlorophenylamido)]propenoic acid and the reported complexes.

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Authors and Affiliations

  1. Department of Chemistry, GC University, Faisalabad, Pakistan

    M. Z. Ali & S. Shahzadi

  2. Department of Chemistry, Quaid-i-Azam University, 45320, Islamabad, Pakistan

    S. Ali

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  1. M. Z. Ali
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  2. S. Ali
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  3. S. Shahzadi
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Correspondence to S. Ali.

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Ali, M.Z., Ali, S. & Shahzadi, S. Synthesis and characterization of Hg(II) and Zn(II) complexes based on 3-[(4-chlorophenylamido)]propenoic acid. Russ. J. Inorg. Chem. 56, 1752–1756 (2011). https://doi.org/10.1134/S0036023611110027

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  • DOI: https://doi.org/10.1134/S0036023611110027

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