Abstract
Processes were developed for manufacturing mixed magnetoelectric (ME) composites (100 − x) wt % PZTNB-1 + x wt % Ni0.9Co0.1Cu0.1Fe1.9O4 − δ using sol-gel processes to synthesize piezoelectric and magnetostrictive components; these processes provide composite ceramics having different connectivity types with the same composition. When PZTNB-1 prepared by the sol-gel process is used for manufacturing the composites, there is a deep one-way doping of the piezoelectric with ferrite constituents, and this doping considerably reduces the degree of tetragonal distortion of the perovskite unit cell to the point of disappearance. In contrast, when coarse-grained PZTNB-1 powder and a ferrite nanopowder prepared by the sol-gel process are used, undesirable doping is completely inhibited. This type of composite has the highest ME transduction efficiency, by two or more times exceeding the ME ceramics of the same composition manufactured by other processes.
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Original Russian Text © I.V. Lisnevskaya, I.A. Bobrova, T.G. Lupeiko, 2012, published in Zhurnal Neorganicheskoi Khimii, 2012, Vol. 57, No. 1, pp. 91–96.
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Lisnevskaya, I.V., Bobrova, I.A. & Lupeiko, T.G. Comparison of the properties of PZTNB-1 + Ni0.9Co0.1Cu0.1Fe1.9O4 − δ magnetoelectric composites manufactured from components synthesized by Sol-Gel processes. Russ. J. Inorg. Chem. 57, 84–89 (2012). https://doi.org/10.1134/S0036023611090142
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DOI: https://doi.org/10.1134/S0036023611090142