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Bismuth(III) complexing with some N- and N,N-substituted thioureas

  • Physical Chemistry of Solutions
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Abstract

Stability constants at ionic strength I = 2 and 293 K were determined spectrophotometrically for multiligand bismuth(III) complexes with thiourea (Tu), N-phenylthiourea (Ptu), N-phenyl-N′-propylthiourea (Pptu), N,N′-diphenylthiourea (Bptu), and N-allyl-N′-propylthiourea (Aptu). The protonation constants of these ligands in perchloric acid solutions were also determined. The stability of the listed complexes changes in the following order of ligands: aptu > tu > pptu > ptu > bptu. This order coincides with the order of changing protonation constants.

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Authors and Affiliations

  1. Siberian Federal University, ul. Kirenskogo 26, Krasnoyarsk, 660074, Russia

    N. N. Golovnev, G. V. Novikova & A. A. Leshok

Authors
  1. N. N. Golovnev
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  2. G. V. Novikova
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  3. A. A. Leshok
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Additional information

Original Russian Text © N.N. Golovnev, G.V. Novikova, and A.A. Leshok, 2009, published in Zhurnal Neorganicheskoi Khimii, 2009, Vol. 54, No. 2, pp. 374–376.

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Golovnev, N.N., Novikova, G.V. & Leshok, A.A. Bismuth(III) complexing with some N- and N,N-substituted thioureas. Russ. J. Inorg. Chem. 54, 329–331 (2009). https://doi.org/10.1134/S0036023609020296

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  • DOI: https://doi.org/10.1134/S0036023609020296

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