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Solid solutions in the Zn-Co-O system: Physicochemical properties

  • Physicochemical Analysis of Inorganic Systems
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Abstract

Physicochemical analysis is used to study phase equilibria and to design a concentration diagram for the Zn-Co-O system. ZnO-, CoO-, and Co3O4-based mixed crystals with a fixed Zn/Co ratio have different oxygen nonstoichiometry depending on the synthesis and annealing parameters. Metastable clustering is discovered in Zn1 − x CoxO1 + δ wurtzite solid solutions, which exist stably in the range 0 ≤ x ≤ 0.2. Magnetization investigation shows that an antiferromagnetic order exists in homogeneous Zn1 − x CoxO1 + δ grains; this order is conserved up to 625 ± 25 K. The substitution of praseodymium, neodymium, samarium, or europium for zinc(II) cations in Zn0.9Co0.1O1 + δ does not spoil the compensated antiferromagnetism of the wurtzite unit cell.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    G. D. Nipan, V. A. Ketsko & T. N. Kol’tsova

  2. Institute of Radiomaterials, Minsk, Belarus

    A. I. Stognii

  3. Joint Institute of Solid-State and Semiconductor Physics, National Academy of Sciences of Belarus, ul. Brovki 17, Minsk, 220072, Belarus

    K. I. Yanushkevich

  4. Belarussian State University, Leningradskaya ul. 14, Minsk, 220080, Belarus

    V. V. Pan’kov

  5. Voronezh State University, Universitetskaya pl. 1, Voronezh, 394893, Russia

    A. M. Khoviv & A. M. Solodukha

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  1. G. D. Nipan
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  2. V. A. Ketsko
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  3. T. N. Kol’tsova
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  4. A. I. Stognii
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  5. K. I. Yanushkevich
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  6. V. V. Pan’kov
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  7. A. M. Khoviv
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  8. A. M. Solodukha
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Additional information

Original Russian Text © G.D. Nipan, V.A. Ketsko, T.N. Kol’tsova, A.I. Stognii, K.I. Yanushkevich, V.V. Pan’kov, A.M. Khoviv, A.M. Solodukha, 2006, published in Zhurnal Neorganicheskoi Khimii, 2006, Vol. 51, No. 12, pp. 2083–2089.

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Nipan, G.D., Ketsko, V.A., Kol’tsova, T.N. et al. Solid solutions in the Zn-Co-O system: Physicochemical properties. Russ. J. Inorg. Chem. 51, 1961–1967 (2006). https://doi.org/10.1134/S0036023606120199

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  • DOI: https://doi.org/10.1134/S0036023606120199

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