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Microstructure and Tribological Behaviour of NiWCrBSi Coating Produced by Flame Spraying

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Abstract

The application of hard and resistant coatings is a possibility to increase the lifetime of parts exposed to heavy loads and harsh environments. This work is focused on the investigation of mechanical properties of flame sprayed NiWCrBSi coatings, addressing in particular coating microstructure, hardness, friction behaviour and wear mechanisms. Microstructure and phase composition of coatings were characterized by optical microscopy, scanning electron microscopy coupled with energy dispersive X-ray spectroscopy and X-ray diffraction analysis. Microhardness of coated and uncoated samples was measured and their tribological properties were evaluated by ball-on-disk tests under dry conditions at room temperature. The morphology of the worn scar at different sliding conditions was investigated using scanning electron microscopy coupled with energy dispersive X-ray spectroscopy and the corresponding wear profile by 3D profilometry. The coatings presented mainly a heterogeneous lamellar structure, containing inhomogeneities, such as unmelted particles, micro-cracks, oxides and various types of pores. The coatings underwent severe wear at low sliding speeds, where the predominating wear mechanism was identified as massive exfoliation. However, when increasing the sliding speed and the sliding distance, a transition in the predominant wear mechanism was observed, passing from the combination of oxidative/soft abrasive mechanism to fatigue delamination. These results indicate the importance of controlling coating microstructure through process parameters to optimize its tribological behaviour.

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REFERENCES

  1. R. J. Wood, “Tribo-corrosion of coatings: a review,” J. Phys. D: Appl. Phys. 40, 5502 (2007).

    Article  CAS  Google Scholar 

  2. P. L. Fauchais, Heberlein, V. R. Joachim, and M. I. Boulos, Thermal Spray Fundamentals: From Powder to Part (Springer, Berlin, 2014).

    Book  Google Scholar 

  3. F. V. Kiryukhantsev-Korneev, A. V. Novikov, T. B. Sagalova, M. I. Petrzhik, E. A. Levashov, and D. V. Shtansky, “A comparative study of microstructure, oxidation resistance, mechanical, and tribological properties of coatings in Mo–B–(N), Cr–B (N) and Ti–B–(N) systems,” Phys. Met. Metallogr. 118, 1136–1146 (2017).

    Article  CAS  Google Scholar 

  4. G. Bolelli, A. Milanti, L. Lusvarghi, L. Trombi, H. Koivuluoto, and P. Vuoristo, “Wear and impact behaviour of high velocity air-fuel sprayed Fe–Cr–Ni–B–C alloy coatings,” Tribol. Int. 95, 372–390 (2016).

    Article  CAS  Google Scholar 

  5. L. Pawlowski, The Science and Engineering of Thermal Spray Coatings (Wiley, New York, 2008).

    Book  Google Scholar 

  6. N. Salimi, O. Bayat, and A. Heidarpour, “Investigation of TiO2 addition on tribological and corrosion behavior of flame sprayed Al coating,” Phys. Met. Metallogr. 121 (14), 1431–1439 (2020).

    Article  Google Scholar 

  7. S. Amin and H. Panchal, “A review on thermal spray coating processes,” IJCTER 2, 53–61 (2016).

    Google Scholar 

  8. M. A. R. Mojena, A. S. Roca, R. S. Zamora, M. S. Orozco, H. C. Fals, and C. R. C. Lima, “Neural network analysis for erosive wear of hard coatings deposited by thermal spray: Influence of microstructure and mechanical properties,” Wear 376, 557–565 (2017).

    Article  Google Scholar 

  9. C. R. C. Lima, R. Libardi, F. Camargo, H. C. Fals, and V. A. Ferraresi, “Assessment of abrasive wear of nanostructured WC-Co and Fe-Based coatings applied by HP-HVOF, flame, and wire arc spray,” J. Therm. Spray Technol. 23, 1097–1104 (2014).

    Article  CAS  Google Scholar 

  10. Z. Q. Zhang, H. D. Wang, B. S. Xu, and G. S. Zhang, “Characterization of microstructure and rolling contact fatigue performance of NiCrBSi/WC–Ni composite coatings prepared by plasma spraying,” Surf. Coat. Technol. 261, 60–68 (2015).

    Article  CAS  Google Scholar 

  11. M. A. Garrido, A. Rico, M. T. Gómez, M. Cadenas, J. E. Fernández-Rico, and J. Rodríguez, “Tribological and oxidative behavior of thermally sprayed NiCrBSi coatings,” J. Therm. Spray Technol. 26, 517–529 (2017).

    Article  CAS  Google Scholar 

  12. R. A. Svrai, “Resistance of laser-clad chromium–nickel coatings to failure under contact fatigue loading,” Phys. Met. Metallogr. 119, 1013–1021 (2018)

    Article  Google Scholar 

  13. A. E. Zatoka, “Thermal spraying and surfacing using flexible cord materials,” Weld. Int. 14, 135–138 (2000).

    Article  Google Scholar 

  14. A. E. Zatoka and V. A. Vasil’eva, “Flexible cords for the application of protective coatings by the gas flame method,” Chem. Pet. Eng. 28, 740–743 (1992).

    Article  Google Scholar 

  15. J. M. Miguel, J. M. Guilemany, and S. Vizcaino, “Tribological study of NiCrBSi coating obtained by different processes,” Tribol. Int. 36, 181–187 (2003).

    Article  CAS  Google Scholar 

  16. R. Gonzalez, M. Cadenas, R. Fernandez, J. L. Cortizo, and E. Rodríguez, “Wear behaviour of flame sprayed NiCrBSi coating remelted by flame or by laser,” Wear 262, 301–307 (2007).

    Article  CAS  Google Scholar 

  17. R. González, M. A. Garcia, I. Penuelas, M. Cadenas, M. del Rocío Fernández, A. H. Battez, and D. Felgueroso, “Microstructural study of NiCrBSi coatings obtained by different processes,” Wear 263, 619–624 (2007).

    Article  Google Scholar 

  18. W. Zhao, B. Zhao, and D. Kong, “Friction–wear characteristics of high velocity oxygen fuel sprayed NiCrBSi alloy coating at elevated temperatures,” Trans. Indian Inst. Met. 71, 2565–2573 (2018).

    Article  CAS  Google Scholar 

  19. D. Kong and B. Zhao, “Effects of loads on friction–wear properties of HVOF sprayed NiCrBSi alloy coatings by laser remelting,” J. Alloys Compd. 705, 700–707 (2017).

    Article  CAS  Google Scholar 

  20. Š. Houdková, E. Smazalová, M. Vostřák, and J. Schubert, “Properties of NiCrBSi coating, as sprayed and remelted by different technologies,” Surf. Coat. Technol. 253, 14–26 (2014).

    Article  Google Scholar 

  21. D. L. Alontseva, N. V. Prokhorenkova, V. N. Rogoz, S. N. Bratushka, M. V. Il’yashenko, E. L. Onanchenko, A.V. Pshik, and N. A. Makhmudov, “Formation of stable nanostructured phases in plasma-jet-treated Ni–Cr powder coatings,” Phys. Met. Metallogr. 113, 785–794 (2012).

    Article  Google Scholar 

  22. L. Liu, H. Xu, J. Xiao, X. Wei, G. Zhang, and C. Zhang, “Effect of heat treatment on structure and property evolutions of atmospheric plasma sprayed NiCrBSi coatings,” Surf. Coat. Technol. 325, 548–554 (2017).

    Article  CAS  Google Scholar 

  23. M. P. Planche, H. Liao, B. Normand, and C. Coddet, “Relationships between NiCrBSi particle characteristics and corresponding coating properties using different thermal spraying processes,” Surf. Coat. Technol. 200, 2465–2473 (2005).

    Article  CAS  Google Scholar 

  24. Z. Bergant, U. Trdan, and J. Grum, “Effect of high-temperature furnace treatment on the microstructure and corrosion behavior of NiCrBSi flame-sprayed coatings,” Corros. Sci. 88, 372–386 (2014).

    Article  CAS  Google Scholar 

  25. R. Younes, M. A. Bradai, A. Sadeddine, Y. Mouadji, and A. Benabbas, “Influence des post-traitements sur la résistance à l’usure des dépôts en superalliage Ni–Cr–Al–Mo obtenus par projection thermique,” Mater. et Tech. 106, 605 (2018).

    Article  CAS  Google Scholar 

  26. A. Idir, F. Delloro, R. Younes, M. A. Bradai, A. Sadeddine, and A. Benabbas, “Tribological performance of thermally sprayed NiWCrBSi alloy coating by two different oxyacetylene flame stoichiometries,” Trans. IMF 99, 313–323 (2021).

    Article  CAS  Google Scholar 

  27. T. Usana-ampaipong, C. Dumkum, K. Tuchinda, V. Tangwarodomnukun, B. Teeraprawatekul, and H. Qi, “Surface and subsurface characteristics of NiCrBSi coating with different WC amount prepared by flame spray method,” J. Therm. Spray Technol. 28, 580–590 (2019).

    Article  CAS  Google Scholar 

  28. P. Niranatlumpong and H. Koiprasert, “Phase transformation of NiCrBSi–WC and NiBSi–WC arc sprayed coatings,” Surf. Coat. Technol. 206, 440–445 (2011).

    Article  CAS  Google Scholar 

  29. R. Rachidi, B. El Kihel, and F. Delaunois, “Microstructure and mechanical characterization of NiCrBSi alloy and NiCrBSi–WC composite coatings produced by flame spraying,” Mater. Sci. Eng., B 241, 13–21 (2019).

    Article  CAS  Google Scholar 

  30. S. H. Yao, “Tribological behaviour of NiCrBSi–WC (Co) coatings,” Mater. Res. Innov. 18, 2–332 (2014).

    Article  Google Scholar 

  31. C. Zhang, L. Liu, H. Xu, J. Xiao, G. Zhang, and H. Liao, “Role of Mo on tribological properties of atmospheric plasma-sprayed Mo–NiCrBSi composite coatings under dry and oil-lubricated conditions,” J. Alloys Compd.727, 841–850 (2017).

    Article  CAS  Google Scholar 

  32. C. Navas, R. Colaço, J. De Damborenea, and R. Vilar, “Abrasive wear behaviour of laser clad and flame sprayed-melted NiCrBSi coatings,” Surf. Coat. Technol. 200, 6854–6862 (2006).

    Article  CAS  Google Scholar 

  33. N. Kazamer, R. Muntean, P. C. Vălean, D. T. Pascal, G. Mărginean, and V. A. Șerban, “Comparison of Ni-based self-fluxing remelted coatings for wear and corrosion applications,” Materials 14, 3293 (2021).

    Article  CAS  Google Scholar 

  34. K. Simunovic, S. Havrlisan, T. Saric, and D. Vukelic, “Modeling and optimization in investigating thermally sprayed Ni-based self-fluxing alloy coatings: A review,” Materials 13, 4584 (2020).

    Article  CAS  Google Scholar 

  35. K. Simunovic, L. Slokar, and S. Havrlisan, “SEM/EDS investigation of one-step flame sprayed and fused Ni-based self-fluxing alloy coatings on steel substrates,” Philos. Mag. 97, 248–268 (2017).

    Article  CAS  Google Scholar 

  36. S. Havrlisan, K. Simunovic, and D. Vukelic, “Modelling of abrasive wear of Ni-based self-fluxing alloy coatings by the application of experimental design,” Teh. Vjesn.-Tech. Gaz 23, 1687–1693 (2016).

    Google Scholar 

  37. X. Y. Dong, X. T. Luo, S. L. Zhang, and C. J. Li, “A novel strategy for depositing dense self-fluxing alloy coatings with sufficiently bonded splats by one-step atmospheric plasma spraying,” J. Therm. Spray Technol. 29, 173–184 (2020).

    Article  CAS  Google Scholar 

  38. Z. Zeng, S. Kuroda, J. Kawakita, M. Komatsu, and H. Era, “Effects of some light alloying elements on the oxidation behavior of Fe and Ni–Cr based alloys during air plasma spraying,” J. Therm. Spray Technol. 19, 128–136 (2010).

    Article  CAS  Google Scholar 

  39. J. K. Xiao, Y. Q. Wu, W. Zhang, J. Chen, X. L. Wei, and C. Zhang, “Microstructure, wear and corrosion behaviors of plasma sprayed NiCrBSi–Zr coating,” Surf. Coat. Technol. 360, 172–180 (2019).

    Article  CAS  Google Scholar 

  40. S. Liu, X. Zheng, and G. Geng, “Dry sliding wear behavior and corrosion resistance of NiCrBSi coating deposited by activated combustion-high velocity air fuel spray process,” Mater. Des. 31, 913–917 (2010).

    Article  CAS  Google Scholar 

  41. H. L. de Villiers Lovelock, P. W. Richter, J. W. Benson, and P. M. Young, “Parameter study of HP/HVOF deposited WC-Co coatings,” J. Therm. Spray Technol. 7, 97–107 (1998).

    Article  CAS  Google Scholar 

  42. S. Buytoz, M. Ulutan, S. Islak, B. Kurt, and O. N. Çelik, “Microstructural and wear characteristics of high velocity oxygen fuel (HVOF) sprayed NiCrBSi–SiC composite coating on SAE 1030 steel,” Arab. J. Sci. Eng. 38, 1481–1491 (2013).

    Article  CAS  Google Scholar 

  43. K. Kato and K. Adachi, “Wear of advanced ceramics,” Wear 253, 1097–1104 (2002).

    Article  CAS  Google Scholar 

  44. J. Jiang, F. H. Stott, and M. M. Stack, “The role of triboparticulates in dry sliding wear,” Tribol. Int. 31, 245–256 (1998).

    Article  CAS  Google Scholar 

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Abdelhek Idir, Delloro, F., Younes, R. et al. Microstructure and Tribological Behaviour of NiWCrBSi Coating Produced by Flame Spraying. Phys. Metals Metallogr. 123, 1410–1418 (2022). https://doi.org/10.1134/S0031918X22700028

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