Abstract
The results of the comparative study of the microstructure, crystal structure, and mechanical properties in microvolumes of the Fe–25 wt % Mn–2 wt % С alloy crystallized from melt in different structural states—homogeneous and heterogeneous—were presented. The study was performed by means of scanning electron microscopy Energy Dispersive X-Ray Spectroscopy (EDX), electron backscatter diffraction (EBSD), and nanoindentation. The destruction of microheterogeneity in the Fe–Mn–C melts was established to lead to an increase in the dendrite parameter, the size of crystallites, and the fraction of low-angle boundaries under cooling and further crystallization. The surface of austenite dendrites was revealed to contain manganese-rich liquation layers, which had a thickness 〈L〉 = 60 µm and a manganese content of 35–40% and led to deformation nonuniformity of an ingot. The adhesion strength of the liquation layer to the body of an austenite dendrite was estimated as Kint = 9.6–13.1 MPa m0.5 and could not be a reason for the destruction of an ingot.
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REFERENCES
N. Popova, T. Dement, E. Nikonenko, I. Kurzina, and E. Kozlov, “Structure and phase composition of manganese steels modified by alloying elements,” AIP Conf. Proc. 1800, No. 1, 030001 (2017).
O. Grässel and G. Frommeyer, “Effect of martensitic phase transformation and deformation twinning on mechanical properties of Fe–Mn–Si–AI steels,” Mater. Sci. Technol. 14, No. 12, 1213–1217 (2018).
G. Frommeyer and O. Grässel, “High strength TRIP/TWIP and superplastic steels: development, properties, application: 10,” Rev. Met. Paris 95, No. 10, 1299–1310 (1998).
G. Frommeyer, U. Brüx, and P. Neumann, “Supra-ductile and high-strength manganese-TRIP/TWIP steels for high energy absorption purposes,” ISIJ Int. 43, No. 3, 438–446 (2003).
P. S. Popel’, “Metastable microheterogeneity of melts in systems with eutectic and monotectics and its effect on the structure of the alloy after solidification,” Rasplavy, No. 1, 22–48 (2005).
M. Calvo-Dahlborg, P. S. Popel, M. J. Kramer, M. Besser, J. R. Morris, and U. Dahlborg, “Superheat-dependent microstructure of molten Al–Si alloys of different compositions studied by small angle neutron scattering,” J. Alloys Compd. 550, 9–22 (2013).
Y.-X. He, J.-S. Li, J. Wang, and E. Beaugnon, “Liquid−liquid structure transition in metallic melt and its impact on solidification: A review,” Trans. Nonferrous Met. Soc. China 30, 2293−2310 (2020).
R. Kurita and H. Tanaka, “Drastic enhancement of crystal nucleation in a molecular liquid by its liquid–liquid transition,” App. Phys. Sci. 116, No. 50, 24949–24955 (2020).
I. G. Farbenindustrie, U.S. Patent No. GB359425 (1931).
N. N. Stepanova, D. P. Rodionov, Yu. E. Turkhan, V. A. Sazonova, and E. N. Khlystov, “Phase stability of nickel-base superalloys solidified after a high-temperature treatment of the melt,” Phys. Met. Metallogr. 95, No. 6, 602–609 (2003).
M. Yang, J. Pan, X. Liu, M. Dong, S. Xu, and Y. Dong, “Effects of melt overheating on undercooling degree, glass forming ability and crystallization behavior of Nd9Fe70Ti4C2B15 permanent magnetic alloy,” J. Chin. Rare Earth Soc. 34, No. 3, 273–281 (2016).
F. S. Yin, X. F. Sun, J. G. Li, H. R. Guan, and Z. Q. Hu, “Effects of melt treatment on the cast structure of M963 superalloy,” Scr. Mater. 48, No. 4, 425–429 (2003).
R. J. Mostert and G. T. Van Rooyen, “Quantitative assessment of the harden ability increase resulting from a super harden ability treatment,” Metall. Trans. A 15, No. 12, 2185–2191 (1984).
C. Wang, J. Zhang, L. Liu, and H. Fu, “Effect of melt superheating treatment on directional solidification interface morphology of multi-component alloy,” J. Mater. Sci. Technol. 27, No. 7, 668–672 (2011).
L. Wang, L. Bo, M. Zuo, and D. Zhao, “Effect of melt superheating treatment on solidification behavior of uniform Al10Bi54Sn36 monotectic alloy,” J. Mol. Liq. 272, 885–891 (2018).
P. Jia, Z. Gao, X. Hu, Y. Liu, J. Zhang, Z. Yang, X. Teng, D. Zhao, Y. Wang, S. Zhang, and D. Geng, “Correlation of composition, cooling rate and superheating temperature with solidification behaviors and microtructures of Al–Bi–Sn ribbons,” Mater. Res. Express 6, No. 6, 066539 (2019).
H. Su, H. Wang, J. Zhang, M. Guo, L. Liu, and H. Fu, “Influence of melt superheating treatment on solidification characteristics and rupture life of a third-generation Ni-based single-crystal superalloy,” Metall. Mater. Trans. B 49, No. 4, 1537–1546 (2018).
O. A. Chikova, N. I. Sinitsin, and V. V.V’yukhin, “Viscosity of Fe–Mn–C melts,” Russ. J. Phys. Chem. A 95, No. 2, 244–249 (2021). https://doi.org/10.1134/S0036024421020084
N. I. Sinitsin, O. A. Chikova, and V. V.V’yukhin, “Resistivity of Fe–Mn–C melts”, Inorg. Mater. 57, No. 1, 86–93 (2021). https://doi.org/10.1134/S002016852101012X
O. A. Chikova, N. I. Sinitsin, and V. V.V’yukhin, “Parameters of the microheterogeneous structure of liquid 110G13l steel,” Russ. J. Phys. Chem. A 93, No. 8, 1435–1442 (2019). https://doi.org/10.1134/S0036024419080065
O. A. Chikova, N. I. Sinitsin, V. V.V’yukhin, and D. Chezganov, “Microheterogeneity and crystallization conditions of Fe-Mn melts,” J. Cryst. Growth. 527, 125239 (2019). https://doi.org/10.1016/j.jcrysgro.2019.125239
N. I. Sinitsin, O. A. Chikova, and D. Chezganov, “Effect of destruction of microheterogeneity on microstructure and crystal structure of 110G13l steel ingots (Hadfield steel),” Chern. Met., No. 1, 36–42 (2020).
W. C. Oliver and G. M. Pharr, “Measurement of hardness and elastic modulus by instrumented indentation: Advances in understanding and refinements to methodology,” J. Mater. Res. 19, No. 1, 3–20 (2004).
C. Zhang, H. Zhou, and L. Liu, “Laminar Fe-based amorphous composite coatings with enhanced processand microstructure evolution,” Solid State Phenom. 176, 29–34 (2011).
C. Zhang, H. Zhou, and L. Liu, “Laminar Fe-based amorphous composite coatings with enhanced bonding strength and impact resistance,” Acta Mater. 72,239–251 (2014).
T. Watanabe, “An approach to grain boundary design for strong and ductile polycrystals,” Res. Mech. 11, No. 1, 47–84 (1984).
T. Watanabe, “Grain boundary design and control for high temperature materials,” Mater. Sci. Eng., A 166, No. 1–2, 11–28 (1993).
P. Lin, G. Palumbo, U. Erb, and K. T. Aust, “Influence of grain boundary character distribution on sensitization and intergranular corrosion of alloy 600,” Scr. Metall. Mater. 33, No. 9, 1387–1392 (1995).
G. Palumbo, P. J. King, K. T. Aust, U. Erb, and P. C. Lichtenberger, “Grain boundary design and control for intergranular stress-corrosion resistance,” Scr. Metall. Mater. 25, No. 8, 1775–1780 (1991).
B. W. Bennett and H. W. Pickering, “Effect of grain boundary structure on sensitization and corrosion of stainless steel,” Metall. Trans. A 18, No. 6, 1117–1124 (1991).
ACKNOWLEDGMENTS
The equipment of the Ural Center for Shared Use “Modern nanotechnology” UrFU was used.
Funding
The reported study was funded by RFBR, project number 19-33-90198.
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Translated by E. Glushachenkova
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Chikova, O.A., Sinitsin, N.I. & Chezganov, D.S. Effect of Crystallization Conditions on the Microstructure, Crystal Structure, and Mechanical Properties of a Fe–Mn–C Alloy in Microvolumes. Phys. Metals Metallogr. 123, 85–91 (2022). https://doi.org/10.1134/S0031918X22010021
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DOI: https://doi.org/10.1134/S0031918X22010021