Abstract
X-ray diffraction, differential scanning calorimetry, and transmission electron microscopy were used to investigate the thermal stability and peculiarities of nanocrystallization upon heating of amorphous Co65.5S18B10 M 6.5 (M = Cr, Fe) alloys obtained by melt-spinning (MS) and mechanical alloying (MA) of mixtures of elemental components. It is shown that, irrespective of the method of manufacture, the amorphous iron-containing alloys, in general, have a lower thermal stability than the chromium-containg alloys. The thermal stability of MA alloys is lower than that of the MS alloys of the same chemical composition. The processes of nanocrystallization during heating of MS and MA amorphous alloys differ. The first crystallize, when heating, through the formation of intermediate phases, and the second, with the formation of stable crystalline phases directly from the amorphous matrix. After the crystallization, the alloys have a nanocrystalline structure with a crystallite size of about 20 nm and the same phase composition of crystallization products for the alloys of the same nominal composition obtained by MA and MS: ɛ-Co, Co2B, and β-Co2Si for Co65.5Si18B10Cr6.5 and α-Co, Co2B, β-Co2Si, and (Fe,Co)3Si for Co65.5Si18B10Fe6.5. The results are discussed in terms of the excess free volume of the amorphous phase and of the value of its specific surface area.
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References
A. I. Gusev, Nanomaterials, Nanostructures, Nanotechnology (Fizmatlit, Moscow, 2009) [in Russian].
A. L. Greer, “From Metallic Glasses to Nanocrystalline Solids,” Proc. 22nd Risó Int. Symp. on Material Science, Ed. by A. R. Dinesen, M. Eldrup, D. Juul Jensen, et al. (Risó Nat. Lab., Roskilde, Denmark, 2001), pp. 461–481.
K. Lu, “Synthesis of Nanocrystalline Materials from Amorphous Solids,” Adv. Mater. 11, 1127–1128 (1999).
Amorphous Metals, Ed. by K. Suzuki, H. Fujimori, and K. Hashimoto (Butterworths, London, 1983; Metallurgiya, Moscow, 1987)
Y. S. Chen, “Glassy Metals,” Rep. Prog. Phys. 43, 353–432 (1980).
C. Suryanarayana, Mechanical Alloying and Milling (Marcel Dekker, New York, 2004).
J. Bonastre, L. Escoda, J. Saurina, J. J. Suñol, J. D. Santos, M. L. Sánchez, and B. Hernando, “Non-Isothermal Approach to Crystallization Process of a Co-Rich Alloy,” J. Non-Cryst. Solids 354, 5126–5128 (2008).
Binary Alloy Phase Diagrams, Ed. by T.B. Massalski (Am. Soc. Met., Metals Park, 1986).
H. E. Kissinger, “Reaction Kinetics in Differential Thermal Analysis,” Anal. Chem. 29, 1702–1706 (1957).
I. C. Rho, C. S. Yoon, C. K. Kim, T. Y. Byun, and K. S. Hong, “Crystallization of Amorphous Alloy Co68Fe4Cr4Si13B11,” Mater. Sci. Eng., B. 96, 48–52 (2002).
El-E. M. Sherif, K. Akoi, K. Sumiyama, and K. Suzuki, “Cyclic Crystalline-Amorphous Transformations of Mechanically Alloyed Co75Ti25,” Appl. Phys. Lett. 70, 1679–1681 (1997).
S. Sharma and C. Suryanarayana, “Mechanical Crystallization of Fe-Based Amorphous Alloys,” J. Appl. Phys. 102, 083544 (2007).
E. P. Elsukov, V. A. Barinov, V. R. Galakhov, E. E. Yurchikov, and A. E. Ermakov, “Order-Disorder Transition in Fe3Si Alloys upon Mechanical Refinement,” Fiz. Met. Metalloved. 55, 337–340 (1983).
R. J. Hebert and J. H. Perepezko, “Effect of Cold-Rolling on the Crystallization Behavior of Amorphous Al88Y7Fe5 Alloy,” Mater. Sci. Eng., A 375–377, 728–732 (2004).
G. J. Fan, M. X. Quan, and Z. Q. Hu, “Deformation-Enhanced Thermal Stability of an Amorphous Fe80B20 Alloy,” J. Appl. Phys. 80, 6055–6057 (1996).
G. Mazzone, A. Montone, and M. V. Antisari, “Effect of Plastic Flow on the Kinetics of Amorphous Phase Growth by Solid State Reaction in the Ni-Zr System,” Phys. Rev. Lett. 65, 2019–2022 (1990).
Zs. Kovacs, P. Henits, A. P. Zhilyaev, and A. Revesz, “Deformation Induced Primary Crystallization in a Thermally Non-Primary Crystallizing Amorphous Al85Ce8Ni5Co2 Alloy,” Scr. Mater 54, 1733–1737 (2006).
W. H. Jiang, F. E. Pinkerton, and M. Atzmon, “Effect of Strain Rate on the Formation of Nanocrystallites in an Al-Based Amorphous Alloy during Nanoindentation,” J. Appl. Phys. 93, 9287–9290 (2003).
W. H. Jiang and M. Atzmon, “The Effect of Compression and Tension on Shear-Band Structure and Nanocrystallization in Amorphous Al90Fe5Gd5: A High-Resolution Transmission Electron Microscopy Study,” Acta Mater. 51, 4095–4105 (2003).
R. J. Hebert, N. Boucharat, J. H. Perepezko, H. Rösner, and G. Wilde, “Calorimetric and Microstructural Analysis of Deformation-Induced Crystallization Reactions in Amorphous Al88Y7Fe5 Alloy,” J. Alloys Compd. 434–435, 18–21 (2007).
Metastable and Non-Equilibrium Alloys, Ed. by Yu. V. Efimov (Metallurgiya, Moscow, 1988) [in Russian].
K. Saksl, J. Bednarçik, R. Nicula, E. Burkel, S. Roth, and H. Franz, “The Influence of Short-Time Ball-Milling on the Stability of Amorphous CoFeB Alloys,” J. Phys.: Condens. Matter 19, 176215 (2007).
U. Köster, B. Punge-Witteler, and G. Steinbrink, “Surface Crystallization of Metal-Metalloid-Glasses,” Key Eng. Mater. 40–41, 53–62 (1990).
N. Morito, “Surface Crystallization Induced by Selective Oxidation of Boron in Fe-B-Si Amorphous Alloy,” Key Eng. Mater. 40–41, 63–68 (1990).
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Original Russian Text © V.V. Muhgalin, G.A. Dorofeev, M.A. Eremina, V.I. Lad’yanov, I.V. Sapegina, 2011, published in Fizika Metallov i Metallovedenie, 2011, Vol. 112, No. 6, pp. 628–635.
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Muhgalin, V.V., Dorofeev, G.A., Eremina, M.A. et al. Nanocrystallization of the amorphous Co-B-Si alloys formed by melt spinning and mechanical alloying. Phys. Metals Metallogr. 112, 596–602 (2011). https://doi.org/10.1134/S0031918X11060081
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DOI: https://doi.org/10.1134/S0031918X11060081