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Luminescence properties of compounds of europium(III) with quinaldic acid and phosphor-containing neutral ligands

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Abstract

Luminescent complex mixed-ligand compounds of europium(III) with quinaldic acid and phosphor- containing neutral ligands have been obtained. Their composition and structure have been determined. The thermal and spectral-luminescent properties of the obtained complex mixed-ligand compounds of europium( III) have been studied. It is shown that, during thermolysis, a water molecule and neutral ligand are detached in two stages with endothermic effects. It is established that quinaldinate ion is coordinated to europium(III) ion in a bidentate fashion. The Stark structure of the 5 D 0–7 F j (j = 0, 1, 2) transitions in low-temperature luminescence spectra of complex compounds of europium(III) has been analyzed.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, Vladivostok, 690022, Russia

    I. V. Kalinovskaya

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  1. I. V. Kalinovskaya
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Correspondence to I. V. Kalinovskaya.

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Original Russian Text © I.V. Kalinovskaya, 2016, published in Optika i Spektroskopiya, 2016, Vol. 120, No. 6, pp. 948–951.

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Kalinovskaya, I.V. Luminescence properties of compounds of europium(III) with quinaldic acid and phosphor-containing neutral ligands. Opt. Spectrosc. 120, 888–891 (2016). https://doi.org/10.1134/S0030400X16060102

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  • DOI: https://doi.org/10.1134/S0030400X16060102

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