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The mechanism of sensitized anti-stokes luminescence in crystals with adsorbed dyes

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Abstract

We have analyzed regular features of sensitization processes of crystals AgCl, AgCl0.95I0.05, and Zn0.6Cd0.4S to processes of a low-threshold (10−3–10−4 W/cm2) two-quantum excitation of anti-Stokes luminescence by adsorbed molecules and by J and H aggregates of dyes of different classes. The excitation centers of this luminescence are complex and consist of dye molecules and few-atom silver clusters adsorbed nearby. Luminescence-excitation processes involve stages of photoexcitation of adsorbed dye molecules; resonance transfer of electronic excitation energy to adsorbed atoms and few-atom silver clusters, levels of which lie near the middle of the band gap; and their subsequent photoionization.

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Authors and Affiliations

  1. Voronezh State University, Voronezh, 394006, Russia

    O. V. Ovchinnikov, A. N. Latyshev, M. S. Smirnov, N. V. Kvashnina & T. S. Shatskikh

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  1. O. V. Ovchinnikov
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  2. A. N. Latyshev
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  3. M. S. Smirnov
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  4. N. V. Kvashnina
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  5. T. S. Shatskikh
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Correspondence to O. V. Ovchinnikov.

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Dedicated to the 50th Anniversary of the Department of Optics and Spectroscopy of Voronezh State University

Original Russian Text © O.V. Ovchinnikov, A.N. Latyshev, M.S. Smirnov, N.V. Kvashnina, T.S. Shatskikh, 2013, published in Optika i Spektroskopiya, 2013, Vol. 114, No. 4, pp. 603–612.

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Ovchinnikov, O.V., Latyshev, A.N., Smirnov, M.S. et al. The mechanism of sensitized anti-stokes luminescence in crystals with adsorbed dyes. Opt. Spectrosc. 114, 554–562 (2013). https://doi.org/10.1134/S0030400X13040152

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  • DOI: https://doi.org/10.1134/S0030400X13040152

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