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IR spectra of benzaldehyde and its derivatives in different aggregate states

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Abstract

We have measured the IR Fourier-transform spectra of biologically active benzaldehyde and its derivatives in the gas and liquid phases. For compounds of this class, the role played by C=O, OH, and CH groups in intra- and intermolecular has been analyzed. We have revealed spectral features that characterize the participation of C=O groups of unsubstituted benzaldehyde molecules in the occurrence of intermolecular hydrogen bonds C=O...H-C with the formation of molecular dimers of different types. For 2-hydroxybenzaldehyde molecules, spectral data have been obtained that are indicative of the occurrence of intramolecular hydrogen bonds of the C=O...H-C type in solutions. In 2-methoxybenzaldehyde molecules, no intramolecular hydrogen bonds have been observed.

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References

  1. B. Halliwell and J. M. C. Gutteridge, Free Radicals in Biology and Medicine (Oxford Univ. Press, Oxford, 1999).

    Google Scholar 

  2. T. Ohta, M. Watanabe, K. Watanabe, Y. Shirasu, and T. Kada, Food Chem. Toxicol. 24(51), 54 (1986).

    Google Scholar 

  3. H. P. V. Rupasinghe, J. Boutler-Bitzer, T. Ahn, and J. A. Odumeru, Food Reseach International 39, 575 (2006).

    Article  Google Scholar 

  4. A. R. Figueiredo, F. Campos, V. Feitas, and T. Hogg, Food Microbiol. 25, 105 (2008).

    Article  Google Scholar 

  5. M. A. Nayaka Harish, U. V. Sathisha, and S. M. Dharmesh, Food Chem. 119, 1307 (2010).

    Article  Google Scholar 

  6. Z. Zhou, Y. Liu, A.-D. Miao, and Sh.-Q. Wang, Eur. J. Pharmacol. No. 13, 1 (2005).

  7. Z. Zhou, Y. Zhang, X.-R. Ding, S.-H. Chen, J. Yang, X.-J. Wang, G.-L. Jia, H.-Sh. Chenb, X.-Ch. Boa, and Sh.-Q. Wang, Antiviral Res., No. 74, 59 (2007).

  8. M. V. Bel’kov, G. A. Ksendzova, G. I. Polozov, I. V. Skornyakov, V. L. Sorokin, G. B. Tolstorozhev, and O. I. Shadyro, Zh. Prikl. Spektrosk. 76(3), 434 (2009).

    Google Scholar 

  9. M. V. Bel’kov, A. N. Gorbacheva, G. A. Ksendzova, G.I. Polozov, I. V. Skornyakov, V. L. Sorokin, G. B. Tolstorozhev, and O. I. Shadyro, Zh. Prikl. Spektrosk. 77(1), 45 (2010).

    Google Scholar 

  10. M. V. Bel’kov, G. A. Ksendzova, T. F. Raichenok, I. V. Skornyakov, V. L. Sorokin, G. B. Tolstorozhev, and O. I. Shadyro, Zh. Prikl. Spektrosk. 78(1), 5 (2011).

    Google Scholar 

  11. M. V. Bel’kov, G. A. Ksendzova, I. V. Skornyakov, V. L. Sorokin, G. B. Tolstorozhev, and O. I. Shadyro, Zh. Prikl. Spektrosk. 78(2), 215 (2011).

    Google Scholar 

  12. M. V. Bel’kov, G. I. Polozov, I. V. Skornyakov, G. B. Tolstorozhev, and O. I. Shadyro, Zh. Prikl. Spektrosk. 78(3), 427 (2011).

    Google Scholar 

  13. M. V. Bel’kov, S. D. Brinkevich, S. N. Samovich, I. V. Skornyakov, G. B. Tolstorozhev, and O. I. Shadyro, Zh. Prikl. Spektrosk. 78(6), 851 (2011).

    Google Scholar 

  14. O. K. Bazyl’, V. Ya. Artyukhov, G. V. Maier, G. B. Tolstorozhev, T. F. Raichenok, I. V. Skornyakov, O. I. Shadyro, V. L. Sorokin, and G. A. Ksendzova, Opt. Spectrosc. 112(2), 223 (2012).

    Article  ADS  Google Scholar 

  15. A. S. Krylov, A. N. Vtyurin, and Yu. V. Gerasimova, PreprInt. No. 832 (Institut Fiziki SO RAN, Krasnoyarsk, 2005) [in Russian].

  16. R. M. Silverstein, D. J. Webster, and D. J. Kiemle, Spectrometric Identification of Organic Compounds (Wiley, New York, 2005).

    Google Scholar 

  17. J. W. Robinson, E. M. Skelly Frame, and G. M. Frame II, Undergraduate Instrumental Analysis (Marcel Dekker, New York, 2005).

    Google Scholar 

  18. E. Pretsch, P. Byüllmann, and C. Affolter, Structure Determination of Organic Compounds (Springer, Berlin, 2000; Mir, Moscow, 2006).

    Google Scholar 

  19. P. R. Srivastava, D. K. Rai, and S. B. Rai, Pramana J. Phys. 56(6), 823 (2001).

    Article  ADS  Google Scholar 

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Original Russian Text © G.B. Tolstorozhev, I.V. Skornyakov, M.V. Bel’kov, O.I. Shadyro, S.D. Brinkevich, S.N. Samovich, 2012, published in Optika i Spektroskopiya, 2012, Vol. 113, No. 2, pp. 202–207.

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Tolstorozhev, G.B., Skornyakov, I.V., Bel’kov, M.V. et al. IR spectra of benzaldehyde and its derivatives in different aggregate states. Opt. Spectrosc. 113, 179–183 (2012). https://doi.org/10.1134/S0030400X12070247

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  • DOI: https://doi.org/10.1134/S0030400X12070247

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