Abstract
The dichloride complexes of Au(III), Pt(II), and Pd(II) with 2,2′-biquinoline are obtained and characterized by 1H NMR spectroscopy, electronic spectroscopy, and cyclic voltammetry. It is shown that the low efficiency of the metal-ligand (2,2′-biquinoline) interaction leads to almost the same positions of the intraligand bands in the absorption and fluorescence spectra of the complexes and to the closeness of their reduction potentials.
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Original Russian Text © M.A. Ivanov, M.V. Puzyk, K.P. Balashev, 2006, published in Optika i Spektroskopiya, 2006, Vol. 101, No. 1, pp. 111–114.
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Ivanov, M.A., Puzyk, M.V. & Balashev, K.P. Spectroscopic and electrochemical properties of dichlorobenzoquinoline complexes of Au(III), Pt(II), and Pd(II). Opt. Spectrosc. 101, 105–108 (2006). https://doi.org/10.1134/S0030400X06070186
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DOI: https://doi.org/10.1134/S0030400X06070186