Abstract
Impregnation catalysts based on CuO, MnOx, and CuO–MnOx with different Cu/Mn ratios supported on ceramic monoliths of alumina and silica are studied by BET, mercury porosimetry, X-ray diffraction analysis, transmission and scanning electron microscopy, temperature-programmed reduction with H2, diffuse reflectance electron spectroscopy, and differential dissolution. It is found that, in the butane oxidation reaction, CuO–MnOx catalysts exert a synergistic effect, which is attributed to the formation of highly defective phases of complex oxides of the nonstoichiometric spinel type with a large number of interparticle boundaries in the near-surface layers of the support.
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Original Russian Text © N.V. Shikina, S.A. Yashnik, A.A. Gavrilova, L.S. Dovlitova, S.R. Khairulin, G.S. Kozlova, Z.R. Ismagilov, 2018, published in Kinetika i Kataliz, 2018, Vol. 59, No. 4, pp. 517–528.
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Shikina, N.V., Yashnik, S.A., Gavrilova, A.A. et al. Formation of Active Structures in Monolith Copper–Manganese Oxide Catalysts for Air-Heating Devices. Kinet Catal 59, 532–543 (2018). https://doi.org/10.1134/S0023158418040122
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DOI: https://doi.org/10.1134/S0023158418040122