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Kinetics and mechanism of diethyl sulfide oxidation by sodium peroxoborate in aqueous solutions

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Abstract

The kinetics of diethyl sulfide (Et2S) oxidation by aqueous sodium peroxoborate (Na2[В2(О2)2(ОН)4]) solutions in a wide acidity range (from [HClO4] = 1 mol/L to рН 12) has been studied using a kinetic distribution method. The kinetic data together with the results of 11B NMR spectroscopy demonstrate that the monoperoxoborate B(O2H) -3 (OH) and diperoxoborate B(O2H)2(OH) -2 anions are the active species in Et2S oxidation by sodium peroxoborate at рН 8–12. It is assumed that, at a high acidity of the medium ([HClO4] = 0.05–1.0 mol/L), peroxoboric acid (ОН)2ВООН or its protonated form (OH)2BOOH +2 are direct reactants along with Н2О2 and HOOH +2 .

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Authors and Affiliations

  1. Litvinenko Institute of Physical–Organic Chemistry and Coal Chemistry, Donetsk, 83114, Ukraine

    V. L. Lobachev, L. M. Dyatlenko & M. Yu. Zubritskii

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  1. V. L. Lobachev
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  2. L. M. Dyatlenko
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  3. M. Yu. Zubritskii
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Correspondence to V. L. Lobachev.

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Original Russian Text © V.L. Lobachev, L.M. Dyatlenko, M.Yu. Zubritskii, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 6, pp. 751–758.

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Lobachev, V.L., Dyatlenko, L.M. & Zubritskii, M.Y. Kinetics and mechanism of diethyl sulfide oxidation by sodium peroxoborate in aqueous solutions. Kinet Catal 57, 742–749 (2016). https://doi.org/10.1134/S0023158416060094

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  • DOI: https://doi.org/10.1134/S0023158416060094

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