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Kinetics of propylene epoxidation with hydrogen peroxide

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Abstract

The kinetics of propylene oxidation to propylene oxide in the presence of a titanium-containing zeolite in an isopropyl alcohol medium is reported. The influence of the concentrations of the starting substances and reaction products and temperature on the rate of the process is considered. A mathematical model has been derived from the experimental data obtained. The rate constants, adsorption equilibrium constants, and activation energies of the reactions have been calculated.

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References

  1. Ashpina, O. and Kim, S., Khim. Zh., 2007, vol. 6, p. 20.

    Google Scholar 

  2. Gang, Li. and Wang, X., E, Appl. Catal., A, 2002, vol. 236, p. 1.

    Article  Google Scholar 

  3. US Patent 4410501, 1983.

  4. Danov, S.M., Sulimov, A.V., Fedosov, A.E., Ovcharov, A.A., and Sulimova, A.V., Khim. Prom-st. Segodnya, 2009, no. 5, p. 5.

    Google Scholar 

  5. Clerici, M.G. and Inoallina, P., J. Catal., 1993, vol. 140, p. 71.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Dzerzhinsk Polytechnic Institute, Nizhni Novgorod State Technical University, Dzerzhinsk, Nizhegorodskaya oblast, 606026, Russia

    S. M. Danov, A. V. Sulimov, V. A. Kolesnikov & A. A. Ovcharov

Authors
  1. S. M. Danov
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  2. A. V. Sulimov
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  3. V. A. Kolesnikov
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  4. A. A. Ovcharov
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Corresponding author

Correspondence to S. M. Danov.

Additional information

Original Russian Text © S.M. Danov, A.V. Sulimov, V.A. Kolesnikov, A.A. Ovcharov, 2013, published in Kinetika i Kataliz, 2013, Vol. 54, No. 2, pp. 202–207.

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Danov, S.M., Sulimov, A.V., Kolesnikov, V.A. et al. Kinetics of propylene epoxidation with hydrogen peroxide. Kinet Catal 54, 193–198 (2013). https://doi.org/10.1134/S0023158413020031

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  • DOI: https://doi.org/10.1134/S0023158413020031

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